(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE
(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE
  • CAS No.:23204-70-8
Other grades of this product :
(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Basic information
Product Name:(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE
Synonyms:(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE;(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDI;(4S,5R)-45-diphenyloxazolidin-2-one;(-)-cis-4,5-Diphenyl-2-oxazolidinone;(4S,5R)-(-)-cis-Diphenyl-2-oxazolidinone;(4S-cis)-4,5-Diphenyl-2-oxazolidinone;(4S,5R)-cis-4,5-Diphenyloxazolidin-2-one;(4S,5R)-4,5-Diphenyl-2-oxazolidinone
CAS:23204-70-8
MF:C15H13NO2
MW:239.27
EINECS:
Product Categories:Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives
Mol File:23204-70-8.mol
(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Chemical Properties
Melting point 227-232 °C(lit.)
Boiling point 466.6±45.0 °C(Predicted)
density 1.192±0.06 g/cm3(Predicted)
storage temp. Refrigerator
solubility Chloroform (Slightly)
form Solid
pka11.56±0.60(Predicted)
color White to Off-White
optical activity[α]23/D 57±4°, c = 2 in chloroform (or methanol)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Usage And Synthesis
Uses(4S,5R)-(-)-cis-Diphenyl-2-oxazolidinone is used as a catalyst in the enantioselective synthesis of chiral phthalides.
UsesVersatile chiral auxiliary used in a variety of highly diastereoselective reactions such as Michael additions, Diels-Alder reactions, cyclopropanations, and allylations.
(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Preparation Products And Raw materials

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