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| Azimsulfuron Basic information |
| Product Name: | Azimsulfuron | | Synonyms: | 1h-pyrazole-5-sulfonamide,n-(((4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl)-1-m;a8947;dpx47;dpx-a8947;1H-Pyrazole-5-sulfonamide, N-(((4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl)-1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-;Azimsulfuron [iso];In-A 894;N-((4,6-diMethoxypyriMidin-2-yl)carbaMoyl)-1-Methyl-4-(2-Methyl-2H-tetrazol-5-yl)-1H-pyrazole-5-sulfonaMide | | CAS: | 120162-55-2 | | MF: | C13H16N10O5S | | MW: | 424.4 | | EINECS: | | Product Categories: | Herbicide | | Mol File: | 120162-55-2.mol |
| Azimsulfuron Chemical Properties |
| Melting point | 170° | | density | 1.74±0.1 g/cm3(Predicted) | | storage temp. | Sealed in dry,2-8°C | | solubility | Solubility in organic solvents (g/l at 25 °C)
Acetone 26.4
Acetonitrile 13.9
Ethyl acetate 13.0
Dichloromethane 65.9
n‐Hexane <0.2
Methanol 2.1
Toluene 1.8 | | form | neat | | pka | 3.6(at 25℃) | | color | White to Off-White | | Water Solubility | Solubility in water (g/l at 20 °C): 0.072 (pH 5) 1.050 (pH 7) 6.536 (pH 9). | | BRN | 8284859 | | CAS DataBase Reference | 120162-55-2(CAS DataBase Reference) | | EPA Substance Registry System | Azimsulfuron (120162-55-2) |
| Hazard Codes | N | | Risk Statements | 50/53 | | Safety Statements | 60-61 | | RIDADR | UN 3077 9 / PGIII | | HS Code | 29350090 | | Toxicity | LD50 in rats, bobwhite quail, mallard duck (mg/kg): >5000, >2250, >2250 orally; in rats (mg/kg): >2000 dermally (Marquez); LC50 (96 hr) in carp, bluegill sunfish, rainbow trout (ppm): >300, >1000, 154 (Marquez) |
| Azimsulfuron Usage And Synthesis |
| Uses | Herbicide. | | Uses | Azimsulfuron may be used as an analytical reference standard for the determination of the pesticide in:- Paddy field water by direct injection using liquid chromatography-hybrid triple quadrupole-linear ion trap-mass spectrometry (LC-QqLIT-MS).
- Tap and leaching water samples by solid-phase extraction (SPE), followed by LC coupled to tandem mass spectrometry (LC-MS/MS).
| | General Description | Azimsulfuron is a sulfonylurea based pesticide. | | Agricultural Uses | Azimsulfuron (DPX‐A8947) is a new rice herbicide introduced in 1996 by DuPont for the control of broadleaf weeds (including hard‐to‐control perennials). At application rates of 8–20 g a.i. ha−1, it provides superior weed control, including E. crus-galli, when compared with the first‐generation sulfonylurea bensulfuron at 50–75 g a.i. ha−1. Azimsulfuron is targeted to replace or supplement bensulfuron in some applications. In Japan, in planted rice, azimsulfuron is used as a premixture with bensulfuron (6 + 30 g a.i. ha−1) to boost the activity against perennial weeds. Good control has also been reported of other members of the Echinochloa family, such as E. hispidula, E. oryzicola, and E. oryzoides. Other weeds controlled include Alisma lanceolatum, A. plantago‐aquatica, Butomus umbellatus, Cyperus difformis, Scirpus maritimus, S. mucronatus, S. supinus, Heteranthera limosa, Potamogeton nodosus, Ammannia coccinea, A. robusta, Bergia capensis, and Lindernia dubia.
Azimsulfuron is sold under the trade names “Gulliver” and “Azin.” | | Safety Profile | Low toxicity by ingestion,inhalation, skin contact, and intraperitoneal routes. A mildeye irritant. When heated to decomposition it emits toxicvapors of NOx and SOx. | | Safety Profile | Very unstable, explosivecompound. Very sensitive to heat. Samples have explodedduring analytical combustion. When heated todecomposition it emits toxic fumes of NOx. See AZIDES. |
| Azimsulfuron Preparation Products And Raw materials |
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