Bromomethyl methyl ether
Bromomethyl methyl ether
  • CAS No.:13057-17-5
Other grades of this product :
Bromomethyl methyl ether Basic information
Product Name:Bromomethyl methyl ether
Synonyms:METHOXYMETHYL BROMIDE;BROMOMETHYL METHYL ETHER;Bromo(methoxy)methane;bromomethoxy-methan;Ether, bromomethyl methyl;Methane, bromomethoxy-;BROMOMETHYL METHYL ETHER, TECH., 90%;BMME~Methoxymethylbromide
CAS:13057-17-5
MF:C2H5BrO
MW:124.96
EINECS:
Product Categories:Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:13057-17-5.mol
Bromomethyl methyl ether Chemical Properties
Boiling point 87 °C (lit.)
density 1.531 g/mL at 25 °C (lit.)
refractive index n20/D 1.456(lit.)
Fp 80 °F
storage temp. 2-8°C
form clear liquid
Specific Gravity1.531
color Colorless to Light yellow to Light orange
Water Solubility Sparingly soluble in water.
Sensitive Moisture Sensitive
BRN 1730853
CAS DataBase Reference13057-17-5(CAS DataBase Reference)
NIST Chemistry ReferenceBromomethyl methyl ether(13057-17-5)
EPA Substance Registry SystemMethane, bromomethoxy- (13057-17-5)
Safety Information
Hazard Codes Xn
Risk Statements 10-20/21/22-36/37/38-40
Safety Statements 26-36/37
RIDADR UN 1992 3/PG 3
WGK Germany 3
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29091990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Bromomethyl methyl ether Usage And Synthesis
Chemical PropertiesColorless liquid
UsesBromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.
UsesBromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.
Bromomethyl methyl ether Preparation Products And Raw materials
Raw materialsphenylsulfanol-->Tributyl(methoxymethyl)stannane-->Methanol-->Methyl acetate-->Formaldehyde-->Chloromethyl methyl ether-->Dimethoxymethane-->Acetyl bromide
Preparation Products1,4-DIMETHOXYBUTANE-->1-(Bromomethyl)naphthalene

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