| Bromomethyl methyl ether Basic information |
| Product Name: | Bromomethyl methyl ether |
| Synonyms: | METHOXYMETHYL BROMIDE;BROMOMETHYL METHYL ETHER;Bromo(methoxy)methane;bromomethoxy-methan;Ether, bromomethyl methyl;Methane, bromomethoxy-;BROMOMETHYL METHYL ETHER, TECH., 90%;BMME~Methoxymethylbromide |
| CAS: | 13057-17-5 |
| MF: | C2H5BrO |
| MW: | 124.96 |
| EINECS: | |
| Product Categories: | Ethers;Organic Building Blocks;Oxygen Compounds |
| Mol File: | 13057-17-5.mol |
| Bromomethyl methyl ether Chemical Properties |
| Boiling point | 87 °C (lit.) |
| density | 1.531 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 80 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| Specific Gravity | 1.531 |
| color | Colorless to Light yellow to Light orange |
| Water Solubility | Sparingly soluble in water. |
| Sensitive | Moisture Sensitive |
| BRN | 1730853 |
| CAS DataBase Reference | 13057-17-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Bromomethyl methyl ether(13057-17-5) |
| EPA Substance Registry System | Methane, bromomethoxy- (13057-17-5) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 10-20/21/22-36/37/38-40 |
| Safety Statements | 26-36/37 |
| RIDADR | UN 1992 3/PG 3 |
| WGK Germany | 3 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29091990 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| Bromomethyl methyl ether Usage And Synthesis |
| Chemical Properties | Colorless liquid |
| Uses | Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone. |
| Uses | Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone. |
| Bromomethyl methyl ether Preparation Products And Raw materials |
| Raw materials | phenylsulfanol-->Tributyl(methoxymethyl)stannane-->Methanol-->Methyl acetate-->Formaldehyde-->Chloromethyl methyl ether-->Dimethoxymethane-->Acetyl bromide |
| Preparation Products | 1,4-DIMETHOXYBUTANE-->1-(Bromomethyl)naphthalene |
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