1,2-Diphenylethane
1,2-Diphenylethane
  • CAS No.:103-29-7
Other grades of this product :
1,2-Diphenylethane Basic information
Product Name:1,2-Diphenylethane
Synonyms:Bibenzyl,1,2-Diphenylethane, Dibenzyl;Bibenzyl s-Diphenylethane;1,1'-Ethane-1,2-diyldibenzene;Bibenzyl, 99% 100GR;Bibenzyl, 99% 25GR;Bibenzyl, 99% 5GR;ethane,1,2-diphenyl-;sym-Diphenylethane
CAS:103-29-7
MF:C14H14
MW:182.26
EINECS:203-096-4
Product Categories:Pharmaceutical Intermediates;Arenes;Building Blocks;Chemical Synthesis;Organic Building Blocks
Mol File:103-29-7.mol
1,2-Diphenylethane Chemical Properties
Melting point 50-53 °C(lit.)
Boiling point 284 °C(lit.)
density 1.014 g/mL at 25 °C(lit.)
refractive index 1.5704
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Soluble in ether, chloroform
form Crystalline Powder
Specific Gravity1.014
color White to light yellow
Water Solubility PRACTICALLY INSOLUBLE
Merck 14,1198
BRN 508068
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference103-29-7(CAS DataBase Reference)
NIST Chemistry ReferenceBibenzyl(103-29-7)
EPA Substance Registry SystemBibenzyl (103-29-7)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 22-24/25-182.26
WGK Germany 2
RTECS DT4375000
Autoignition Temperature896 °F
Hazard Note Irritant
TSCA Yes
HS Code 29029090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,2-Diphenylethane Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder. soluble in chloroform, ether, carbon disulfide and amyl acetate, soluble in alcohol, almost insoluble in water. It reacts with chromium trioxide or permanganic acid to generate benzoic acid.
Uses1,2-Diphenylethane is used as solvent for nitro fibre and in synthesis of other organic chemical products.
Preparation1,2-Diphenylethane is synthesized by the action of benzyl chloride with sodium metal. Or from the reaction of benzyl chloride in the presence of copper, or from the hydrogenation of benzoin in the presence of nickel.
DefinitionChEBI: 1,2-dihydrostilbene is a diphenylethane that is the 1,2-dihydro derivative of stilbene.
Synthesis Reference(s)Chemical and Pharmaceutical Bulletin, 36, p. 1529, 1988 DOI: 10.1248/cpb.36.1529Journal of the American Chemical Society, 81, p. 1243, 1959 DOI: 10.1021/ja01514a057
Purification MethodsCrystallise bibenzyl from hexane, MeOH, or 95% EtOH. It has also been sublimed under vacuum, and further purified by percolation through columns of silica gel and activated alumina. [Beilstein 5 IV 1868.]

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