rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
  • CAS No.:100163-29-9
Other grades of this product :
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Basic information
Stability Storage
Product Name:rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
Synonyms:RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV);RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM;(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV);DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
CAS:100163-29-9
MF:C20H24Cl2Zr10*
MW:426.53
EINECS:
Product Categories:metallocene;Zr;Catalysis and Inorganic Chemistry;Chemical Synthesis;Zirconium
Mol File:100163-29-9.mol
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties
Melting point 267-271 °C(lit.)
form Powder
color white to pale yellow
Sensitive moisture sensitive
Safety Information
Hazard Codes C,Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-45-36
RIDADR UN 3261 8/PG 2
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Usage And Synthesis
StabilityStable under normal temperature and pressure, avoid contact with water and oxidants.
Storagesealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.
UsesRac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.
UsesCatalyst for:Regiochemistry in Negishi carboaluminationsPolymerization of olefinsDiastereoselective intramolecular olefin alkylationsAsymmetric carbomagnesiationReduction of esters to alcoholsEnantioselective synthesis of allylic amines
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Preparation Products And Raw materials

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