![[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)](/img/67292-34-6.jpg "[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)")
| [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Basic information |
| Product Name: | [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) |
| Synonyms: | Ni(dppf)Cl2;DPPF·NICL2;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE;[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) DICHLORIDE;[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLORONICKEL(II);DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II);(1,1'-bis(diphenylphosphino)ferrocene)-dichloroni;[1, 1’-Bis(diphenyphosphino)ferrocene]dichloronickel(II) |
| CAS: | 67292-34-6 |
| MF: | C34H22Cl2FeNiP2 |
| MW: | 677.94 |
| EINECS: | |
| Product Categories: | Ni;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;pharmacetical;Metal Complexes;Metallocenes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Metal Compounds |
| Mol File: | 67292-34-6.mol |
| [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Chemical Properties |
| Melting point | 285 °C (dec.)(lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | crystal |
| color | green micro |
| Water Solubility | Insoluble in water. |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Safety Information |
| Hazard Codes | T |
| Risk Statements | 45-42/43 |
| Safety Statements | 53-22-36/37/39-45 |
| RIDADR | 2811 |
| WGK Germany | 3 |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Usage And Synthesis |
| Chemical Properties | Yellow powder |
| Uses | diphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals. |
| Uses | (1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines. |
| Uses | suzuki reaction |
| [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Preparation Products And Raw materials |
| Raw materials | Ethanol-->Dichloromethane-->Nickel(II) chloride hexahydrate-->1,1'-Bis(diphenylphosphino)ferrocene |
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