IRON(III) PERCHLORATE HYDRATE
IRON(III) PERCHLORATE HYDRATE
  • CAS No.:13537-24-1
Other grades of this product :
IRON(III) PERCHLORATE HYDRATE Basic information
Product Name:IRON(III) PERCHLORATE HYDRATE
Synonyms:Perchloricacid,iron(3+)salt;perchloricacid,iron(3++)salt;IRON PERCHLORATE;IRON(III) PERCHLORATE HYDRATE (PURPLE);IRON(III) PERCHLORATE HYDRATE, LOW CHLORIDE;IRON(III) PERCHLORATE HYDRATE;IRON(III) PERCHLORATE N-HYDRATE;IRON (III) PERCHLORATE HYDRATE, YELLOW
CAS:13537-24-1
MF:Cl3FeH2O13
MW:372.21
EINECS:236-908-0
Product Categories:Inorganics
Mol File:13537-24-1.mol
IRON(III) PERCHLORATE HYDRATE Chemical Properties
form crystalline
color yellow
Sensitive Hygroscopic
CAS DataBase Reference13537-24-1
EPA Substance Registry SystemPerchloric acid, iron(3+) salt (13537-24-1)
Safety Information
Hazard Codes O,Xi
Risk Statements 8-36/37/38
Safety Statements 17-26-27
RIDADR UN 1481 5.1/PG 2
WGK Germany 3
HazardClass 5.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
IRON(III) PERCHLORATE HYDRATE Usage And Synthesis
Chemical Propertiesyellow crystal(s); hygroscopic [STR93]
PreparationThis crystallizes as the pale pink decahydrate Fe(ClO4)3.10H2O from solutions of iron(III) chloride or hydrous iron(III) oxide in perchloric acid. Upon standing over phosphorus pentoxide the decahydrate becomes the hexahydrate ; a 9-hydrate crystallizes from solution above 42°. This salt has been important in the study of the hydrated Fe3+ ion since perchlorate ions have only very low coordinating ability.
Purification MethodsCrystallise it twice from conc HClO4, the first time in the presence of a small amount of H2O2 to ensure that the iron is fully oxidised [Sullivan J Am Chem Soc 84 4256 1962]. Extreme care should be taken with this preparation because it is potentially EXPLOSIVE.
IRON(III) PERCHLORATE HYDRATE Preparation Products And Raw materials
Preparation Products4-Vinylcyclohexene dioxide

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