1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
  • CAS No.:4526-07-2
Other grades of this product :

1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE Basic information
Product Name:1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
Synonyms:1,4-BIS-(TRIMETHYLSILYL)-1,3-BUTADIYNE, 98%1,4-BIS-(TRIMETHYLSILYL)-1,3-BUTADIYNE, 98%1,4-BIS-(TRIMETHYLSILYL)-1,3-BUTADIYNE, 98%;1,4-Bis(trimethylsilyl)-1,3-butanediyne;1,4-Bis(trimethylsilyl)-1-butyne-3-yne;1,4-Bis(trimethylsilyl)butane-1,3-diyne;1,4-Di(trimethylsilyl)-1,3-butadiyne;Bis(trimethylsilyl)-1,3-butadiyne;4-Bis(trimethylsilyl)-1,3-butadiyne;1,4-Bis(trimethylsilyl)buta-1,3-diyne
CAS:4526-07-2
MF:C10H18Si2
MW:194.42
EINECS:629-258-8
Product Categories:Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Diyne Compounds (LB Films);LB Films;Acetylenes;Synthetic Organic Chemistry;Ethynylsilanes;Functional Materials;Functionalized Acetylenes;Si (Classes of Silicon Compounds);Alkynes;Building Blocks;Chemical Synthesis;Internal;Organic Building Blocks
Mol File:4526-07-2.mol
1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE Chemical Properties
Melting point 111-113 °C(lit.)
Boiling point 197.7±23.0 °C(Predicted)
density 0.974 g/mL at 20 °C(lit.)
refractive index n20/D1.384(lit.)
Fp >45°C
storage temp. 2-8°C
form solid
color White to Light yellow to Light orange
Water Solubility Insoluble in water.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 1758268
InChIKeyLBNVCJHJRYJVPK-UHFFFAOYSA-N
CAS DataBase Reference4526-07-2(CAS DataBase Reference)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-22-24/25
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
TSCA No
HazardClass 4.1
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrichEnglish
ACROSEnglish
ALFAEnglish
1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE Usage And Synthesis
Chemical Propertieslight yellow to light beige cryst.powder or flakes
Uses1,4-Bis(trimethylsilyl)-1,3-butadiyne is used in Negishi protocol for the synthesis of glycosylated oligo(ethynylene)s. It is also used as pharmaceutical intermediates.
Uses1,4-Bis(trimethylsilyl)butadiyne can be used as a reagent to prepare:
  • 1,1,3,4-Tetrasilyl-substituted 1,3-butadienes or 1,1,3,4-tetrasilyl-substituted 1,2-butadienes by hydrosilylation reaction using various hydridosilanes and catalysts.

  • Glycosylated oligo(ethynylene)s using the Negishi reaction.

  • (±) Falcarinol, a polyacetylene class of fatty alcohol.

1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE Preparation Products And Raw materials
Preparation Products2,7-DIMETHYL-3,5-OCTADIYN-2,7-DIOL

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