| 1-(TRIISOPROPYLSILYL)PYRROLE Basic information |
| Product Name: | 1-(TRIISOPROPYLSILYL)PYRROLE |
| Synonyms: | 1-TRIISOPROPYLSILANYL-1H-PYRROLE;1-(TRIISOPROPYLSILYL)PYRROLE;N-TRIISOPROPYLSILYL PYRROLE;tri(propan-2-yl)-(1-pyrrolyl)silane;1-[tris(propan-2-yl)silyl]-1H-pyrrole;1-(Triisopropylsilyl)pyrrole 95%;1H-Pyrrole, 1-[tris(1-Methylethyl)silyl]-;1-(Triisopropylsilyl)-1H-pyrrole |
| CAS: | 87630-35-1 |
| MF: | C13H25NSi |
| MW: | 223.43 |
| EINECS: | |
| Product Categories: | Pyrrole&Pyrrolidine&Pyrroline;Functional Materials;Pyrroles (for Conduting Polymer Research);Reagents for Conducting Polymer Research;Si (Classes of Silicon Compounds);Si-N Compounds;Trimethylsilylazide, etc.;Building Blocks;Heterocyclic Building Blocks;Pyrroles |
| Mol File: | 87630-35-1.mol |
| 1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties |
| Boiling point | 78 °C0.4 mm Hg(lit.) |
| density | 0.904 g/mL at 25 °C(lit.) |
| refractive index | n |
| Fp | 224 °F |
| storage temp. | Inert atmosphere,2-8°C |
| pka | -2.55±0.70(Predicted) |
| form | clear liquid |
| Specific Gravity | 0.904 |
| color | Colorless to Almost colorless |
| Water Solubility | Not miscible in water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 3540663 |
| CAS DataBase Reference | 87630-35-1(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 20-22-36 |
| Safety Statements | 24/25-26 |
| WGK Germany | 3 |
| HS Code | 2933998090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| 1-(TRIISOPROPYLSILYL)PYRROLE Usage And Synthesis |
| Uses | 1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc). |
| Uses | 1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:
|
| General Description | 1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc). |
| 1-(TRIISOPROPYLSILYL)PYRROLE Preparation Products And Raw materials |
| Preparation Products | NSC 87241-->1-(Triisopropylsilyl)pyrrole-3-boronic acid |
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