meso-Tetra(4-carboxyphenyl)porphine Basic information |
Product Name: | meso-Tetra(4-carboxyphenyl)porphine |
Synonyms: | TETRACARBOXYPHENYLPORPHYRIN;TETRAKIS(4-CARBOXYPHENYL)PORPHINE;RARECHEM AS SA 0048;NICKEL IONOPHORE II;MESO-TETRA(4-CARBOXYPHENYL)PORPHINE;MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID;5,10,15,20-TETRA(4-CARBOXYPHENYL)PORPHYRIN;5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN |
CAS: | 14609-54-2 |
MF: | C48H30N4O8 |
MW: | 790.77 |
EINECS: | |
Product Categories: | porphine (porphyrin) ligand;Porphyrins;Synthetic Porphyrins;Analytical Chemistry;Biochemistry;Chelating Reagents;Ligands for Pharmaceutical Research;Magnetic Resonance Imaging (Chelating Reagents);Porphines |
Mol File: | 14609-54-2.mol |
meso-Tetra(4-carboxyphenyl)porphine Chemical Properties |
Melting point | >300 °C |
density | 1.462±0.06 g/cm3(Predicted) |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
form | Powder |
color | purple |
Safety Information |
Safety Statements | 22-24/25 |
WGK Germany | 3 |
RTECS | DH6488300 |
HS Code | 2933998090 |
Hazardous Substances Data | 14609-54-2(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
meso-Tetra(4-carboxyphenyl)porphine Usage And Synthesis |
Uses | meso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes. |
Uses | Nickel ionophore II is a selective sensor for Ni(II) ions. |
Uses | 4,4′,4′′, 4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) (H2TCPP) can be used to fabricate three dimensional Ru polymer complex. It can be grafted on SiO2/Nb2O5 substrate and subsequently metallized to investigate catalytic oxidation of hydrazine. |
General Description | Visit our Sensor Applications portal to learn more. |
Synthesis | General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent). |
meso-Tetra(4-carboxyphenyl)porphine Preparation Products And Raw materials |
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