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| Carbonylchlorohydrotris(triphenylphosphine)ruthenium Basic information | | Reaction |
| Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties |
| Melting point | 204-206 °C (dec.)(lit.) | | Boiling point | approximate 360℃ | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | Powder | | color | Cream to tan | | Water Solubility | insoluble | | Sensitive | Air stable, light sensitive |
| Carbonylchlorohydrotris(triphenylphosphine)ruthenium Usage And Synthesis |
| Reaction |
- Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
- Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
- Catalyst for amination of alcohols with ammonia.
| | Chemical Properties | pale yellow crystals | | Uses | Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR). |
| Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials |
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