TRANS-2-DODECENAL
TRANS-2-DODECENAL
  • CAS No.:20407-84-5
Other grades of this product :
TRANS-2-DODECENAL Basic information
Product Name:TRANS-2-DODECENAL
Synonyms:3-NONYLACROLEIN;trans-2-Dodecen-1-yl Aldehyde;2-Dodecenal, (E)-;Einecs 243-797-2;(E)-dodec-2-enal;(E)-2-Dodecen-1-al;(E)-2-dodecenal;trans-Dodec-2-enal
CAS:20407-84-5
MF:C12H22O
MW:182.3
EINECS:243-797-2
Product Categories:Alphabetical Listings;C-D;Flavors and Fragrances
Mol File:20407-84-5.mol
TRANS-2-DODECENAL Chemical Properties
Melting point 2°C (estimate)
Boiling point 93 °C0.5 mm Hg(lit.)
density 0.849 g/mL at 25 °C(lit.)
vapor pressure 34Pa at 25℃
refractive index n20/D 1.457(lit.)
Fp >230 °F
Water Solubility 3.21mg/L at 20℃
BRN 2434537
LogP4.892 at 25℃
CAS DataBase Reference20407-84-5(CAS DataBase Reference)
EPA Substance Registry System2-Dodecenal, (2E)- (20407-84-5)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 1760 8/PG 3
WGK Germany 2
RTECS JR5150000
10-23
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
TRANS-2-DODECENAL Usage And Synthesis
Chemical Properties2-Dodecenal is a colorless liquid with a powerful aldehydic, mandarin, citrus-like odor. It may be prepared as described earlier, see 2-hexenal,. 2-Dodecenal is used in flavors and fragrances to create orangemandarin- like citrus notes.
Chemical Properties2-Dodecenal has a powerful, fatty, citrus-like odor at low levels and a mandarin taste.
OccurrenceReported found in orange peel oil, kumquat peel oil, milk (0.0006 ppm), grilled and roasted beef, cured pork, roasted peanut (0.02 to 0.11 ppm), coriander leaf and unprocessed rice. Its presence has also been reported in the essential oils of Eryngium facidum and Achasma walang Val.
UsesTrans-2-Dodecenal is a component of essential oils from Cymbocarpum anethoides and a volatile compound of virgin rapeseed oil.
DefinitionChEBI: A trans-2,3-unsaturated fatty aldehyde that is (E)-dodec-2-ene in which the allylic methyl group has been oxidised to the corresponding aldehyde.
PreparationBy condensation of acetaldehyde with decanal; also from α-bromolauric acid by way of the ethyl ester and alcohol.
Aroma threshold valuesDetection: 1.4 ppb; aroma characteristics at 0.1% in neobee oil: fatty, waxy, metallic, fatty tallow, greasy, meaty, green vegetative cucumber with chicken and cilantro notes.
Taste threshold valuesTaste characteristics at 0.1 ppm: strong aldehydic, soapy, vegetative green, celery and cucumber-like, banana musty, chicken fatty and brothy.
Flammability and ExplosibilityNonflammable
Trade nameMandarin Aldehyde (Firmenich).
TRANS-2-DODECENAL Preparation Products And Raw materials
Preparation ProductsTRANS-2-DODECENOIC ACID

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