| 2-Nitroso-1-naphthol Basic information |
| Product Name: | 2-Nitroso-1-naphthol |
| Synonyms: | C.I.Oxidation Base 15;2-Nitroso-1-naphthol,95%;1,2-NaphthoquinoneiMine-2-oxiMe;1-Naphthalenol,2-nitroso-;1-Naphthol, 2-nitroso-;2-nitroso-1-naphthaleno;Nitroso-1-napht;2-nitroso-1-Naphthalenol |
| CAS: | 132-53-6 |
| MF: | C10H7NO2 |
| MW: | 173.17 |
| EINECS: | 205-064-5 |
| Product Categories: | Piperazine derivates;Nitroso Compounds;Intermediates of Dyes and Pigments;Nitrogen Compounds;Organic Building Blocks |
| Mol File: | 132-53-6.mol |
| 2-Nitroso-1-naphthol Chemical Properties |
| Melting point | 150-155 °C (dec.)(lit.) |
| Boiling point | 303.81°C (rough estimate) |
| density | 1.2427 (rough estimate) |
| refractive index | 1.5200 (estimate) |
| pka | 7.47±0.10(Predicted) |
| form | Solid |
| color | Yellow needles from H2O or C6H6 |
| Odor | Odorless |
| Water Solubility | SLIGHTLY SOLUBLE |
| BRN | 1867919 |
| CAS DataBase Reference | 132-53-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-Naphthalenol, 2-nitroso-(132-53-6) |
| EPA Substance Registry System | 1-Naphthalenol, 2-nitroso- (132-53-6) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
| RTECS | QL4550000 |
| F | 8 |
| HS Code | 2929900090 |
| Hazardous Substances Data | 132-53-6(Hazardous Substances Data) |
| Toxicity | LD orl-rat: >500 mg/kg NCNSA6 5,35,53 |
| MSDS Information |
| Provider | Language |
|---|---|
| 2-Nitroso-1-naphthol | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 2-Nitroso-1-naphthol Usage And Synthesis |
| Chemical Properties | yellow-greenish to yellow-brownish powder |
| General Description | 2-nitroso-1-naphthol helps in the extraction of cobalt ion as it is used as a selective complexing agent. It is used in the separation and preconcentration of Th(IV), Ti(IV), Fe(III), Pb(II) and Cr(III) by solid phase extraction. |
| Safety Profile | Moderately toxic by ingestion. Many nitroso compounds are carcinogens. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS. |
| Purification Methods | Purify the naphthol by recrystallisation from pet ether (b 60-80o) or by dissolving it in hot EtOH, followed by successive addition of small volumes of water (m 158o dec). It also crystallises from *C6H6 or H2O. Crystallisation from *C6H6/pet ether gives m (106-109 o, also 109.5o). It has max at 274.5 and 382nm (CHCl3). It complexes with metals. [Beilstein 7 H 712, 7 I 385, 7 II 647, 7 III 3688, 7 IV 2419.] |
| 2-Nitroso-1-naphthol Preparation Products And Raw materials |
| Raw materials | 1-Naphthol-->Congo red paper-->1,4-Naphthoquinone 1-oxime-->4-nitrosonaphthalen-1-ol-->1-Hydroxy-2-naphthoic acid-->2-NITRONAPHTHALENE-->2-Naphthylamine-->1,2-NAPHTHOQUINONE-->Cyclopropylamine |
| Preparation Products | 2-Nitro-1-naphthol |
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