Phthaloyl dichloride
Phthaloyl dichloride
  • CAS No.:88-95-9
Other grades of this product :
Phthaloyl dichloride Basic information
Product Name:Phthaloyl dichloride
Synonyms:benzenedioylchloride;Phthalic chloride;Phthalic dichloride;Phthalyl dichloride;1,2-Bis(chlorocarbonyl)benzene;o-Phtaloyl chloride;o-Phthalic acid dichloride;O-Phthaloyl dichloride, 90%, remainder mainly phthalic acid
CAS:88-95-9
MF:C8H4Cl2O2
MW:203.02
EINECS:201-869-0
Product Categories:ACID CHLORIDES;o-Phthaloyl Dichloride, o-Diacetyl Chloride
Mol File:88-95-9.mol
Phthaloyl dichloride Chemical Properties
Melting point 6-12 °C(lit.)
Boiling point 269-271 °C(lit.)
density 1.409 g/mL at 25 °C(lit.)
vapor pressure 30 mm Hg ( 47 °C)
refractive index n20/D 1.568(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility Miscible with ether.
form Liquid
color Clear yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
Merck 14,7375
BRN 608200
CAS DataBase Reference88-95-9(CAS DataBase Reference)
NIST Chemistry Reference1,2-Benzenedicarbonyl dichloride(88-95-9)
EPA Substance Registry System1,2-Benzenedicarbonyl dichloride (88-95-9)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
21
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29173980
MSDS Information
ProviderLanguage
1,2-Benzenedicarbonyl dichloride English
SigmaAldrich English
ACROS English
ALFA English
Phthaloyl dichloride Usage And Synthesis
Chemical Propertiescolorless or clear yellow oily liquid. decompose with water and alcohol, soluble in ether, chloroform and benzene.
UsesPhthaloyl chloride is used for the preparation of volatile acid chlorides from the acids. It acts as a trapping agent for the nitrite ion in the fluorodenitration of aromatic substrates with potassium fluoride. It serves as an additive in polymers and fibers to improve the color stability. It is used as an ingredient in ceramic mold binders, as a stabilizer for polymers and in reverse osmosis membranes.
Useso-Phthaloyl Dichloride is used in the phthaloylation of hemicelluloses as an efficient way to improve their lipophilicity and hydrophilicity. Phthaloylation of hemicelluloses is also a key precursor to preparing polysaccharide derivatives.
PreparationSynthesis of phthaloyl dichloride: Mix 148g of phthalic anhydride with 220g of phosphorus pentachloride, heat, gradually increase the temperature to 250°C, escape the phosphorus oxychloride, distill the reaction product under reduced pressure, collect the 131-133°C (1.2-1.33kPa) fraction to obtain 187g of phthaloyl dichloride.
General Descriptionequilibrium mixture (phthaloyl chloride ~80% and pseudochloride ~10%) both components show equal chemical behaviour
Phthaloyl dichloride Preparation Products And Raw materials
Preparation ProductsAdmire-->HEPTENOPHOS-->Fumaryl chloride-->Milnacipran Related Impurity 3-->Tetrachlorophthalic acid-->DIBENZYL PHTHALATE

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