(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Eight Chongqing Chemdad Co. ，Ltd

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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

CAS No.：155830-69-6

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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Basic information

Product Name:	(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms:	(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG;(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%;-2-(Diphenylphosphino);ferrocenyl]ethyldi-tert-butylphosphine;"Josiphos SL-J002-1/ (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine";Josiphos SL-J002;Josiphos SL-J002-1 / (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
CAS:	155830-69-6
MF:	C32H40FeP210*
MW:	542.45
EINECS:
Product Categories:	Chiral Phosphine;Ferrocene Series;organophosphine ligand;Josiphos Series
Mol File:	155830-69-6.mol

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties

Melting point	218-220°C (dec.)
alpha	-412° ±15° (c 0.5, CHCl3)
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform, Methanol
form	Powder
color	Orange

Safety Information

Risk Statements	20/21/22-36/37/38
Safety Statements	24/25
WGK Germany	3
F	10
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Usage And Synthesis

Reaction	Ligand for Palladium-catalyzed amination of aryl halides Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties	Orange powder
Uses	It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General Description	(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-^tBu) is a chiral ferrocenyl diphosphine ligand.

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Hydrochloric acid-->Ethyl acetate-->Dichloromethane-->Acetic acid-->Potassium carbonate-->Acetic anhydride-->n-Butyllithium-->Lithium Aluminum Hydride-->Magnesium-->Phosphorus trichloride-->2-Chloro-2-methylpropane-->Chlorodiphenylphosphine-->(R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE

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