Chloromethyltrimethylsilane
Chloromethyltrimethylsilane
  • CAS No.:2344-80-1
Other grades of this product :

Chloromethyltrimethylsilane Basic information
Product Name:Chloromethyltrimethylsilane
Synonyms:CHLOROMETHYLTRIMETHYLSILANE;Chloromethyltrimethylsilane, 98+%;Silane, (chloromethyl)trimethyl-;chlormethyl-trimethyl-silane;Chloro(trimethylsilyl)methane;ChloroMethyltriMethylsilane, 98+% 100GR;ChloroMethyltriMethylsilane, 98+% 25GR;(CHLOROMETHYL)TRIMETHYLSILANE FOR SYNTHE
CAS:2344-80-1
MF:C4H11ClSi
MW:122.67
EINECS:219-058-5
Product Categories:pharmacetical;Halides;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Chemical Synthesis;Organometallic Reagents;Organosilicon;Others
Mol File:2344-80-1.mol
Chloromethyltrimethylsilane Chemical Properties
Melting point <0°C
Boiling point 98-99 °C(lit.)
density 0.88 g/mL at 20 °C
vapor pressure ~25 mm Hg ( 20 °C)
refractive index n20/D1.418(lit.)
Fp 27 °F
storage temp. Store below +30°C.
form Liquid
Specific Gravity0.879
color Clear colorless
Water Solubility insoluble
Sensitive Moisture Sensitive
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 906705
CAS DataBase Reference2344-80-1(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, (chloromethyl)trimethyl-(2344-80-1)
EPA Substance Registry SystemSilane, (chloromethyl)trimethyl- (2344-80-1)
Safety Information
Hazard Codes F,Xi,C
Risk Statements 11-36/37/38-34
Safety Statements 16-26-36-29-37/39-33
RIDADR UN 1993 3/PG 2
WGK Germany 3
10-21
Hazard Note Irritant/Highly Flammable
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095
MSDS Information
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Chloromethyltrimethylsilane Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
Uses(Chloromethyl)trimethylsilane is used for Wittig reaction and building blocks.
Uses(Chloromethyl)trimethylsilane can be treated with aldehydes or ketones in the presence of triphenylphosphine to synthesize terminal alkenes. It can also be used in the preparation of a reagent, trimethylsilylmethyl magnesium chloride, commonly used in Peterson methylenation.
Chloromethyltrimethylsilane Preparation Products And Raw materials
Raw materialsChloro(chloromethyl)dimethylsilane-->Bromochloromethane-->(Chloromethyl)trichlorosilane-->METHYLMAGNESIUM IODIDE-->Tetramethylsilane
Preparation Products(TRIMETHYLSILYL)DIAZOMETHANE-->N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine-->TRIMETHYLSILYLMETHYL ACETATE-->(METHOXYMETHYL)TRIMETHYLSILANE-->1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane-->TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

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