Other grades of this product :
| Product Name: | XPhos Pd G2 | | Synonyms: | Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [XPhos Palladacycle];Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II);Chloro(2-dicyclohexylphosphin;(SP-4-4)-[2'-Amino[1,1'-biphenyl]-2-yl]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium;2nd Generation XPhos Precatalyst;X-Phos aminobiphenyl palladium chloride precatalyst;Palladium-Xphos;-biphenyl-2-yl) palladium(II), min. 98% | | CAS: | 1310584-14-5 | | MF: | C45H58ClNPPd+2 | | MW: | 785.795481 | | EINECS: | | Product Categories: | Pd;Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series | | Mol File: | 1310584-14-5.mol |
| XPhos Pd G2 Chemical Properties |
| Melting point | 202-210°C | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | color | white | | InChIKey | USWOVTRTHZODCW-UHFFFAOYSA-N |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 |
| XPhos Pd G2 Usage And Synthesis |
| Appearance |
Turquoise or grey or dark green powder
| | Reaction | Palladium precatalyst for Suzuki-Miyaura coupling reactions.
| | Uses | XPhos Pd G2 is a used as a catalyst in chemical reactions. | | Uses | XPhos Pd G2 was employed as catalyst in the following reactions:- Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
- Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
- Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.
| | General Description | XPhos Pd G2 is a bulky monodentate biaryl ligand. It is aBuchwald′s 2nd generation preformed catalyst. It undergoesrapid reductive elimination to form a reactive, monoligated Pd(0) species. |
| XPhos Pd G2 Preparation Products And Raw materials |
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