(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Seven Chongqing Chemdad Co. ，Ltd

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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

CAS No.：148461-14-7

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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Basic information

Product Name:	(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
Synonyms:	(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
CAS:	148461-14-7
MF:	C24H24NOP
MW:	373.43
EINECS:
Product Categories:	Chiral Phosphine;PHOX Series;organophosphine ligand
Mol File:	148461-14-7.mol

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties

Melting point	85-90 °C
alpha	-44° (c 1.4, CHCl3)
Boiling point	492.7±28.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	4.31±0.70(Predicted)
form	Powder
color	white
optical activity	[α]20/D 48±3°, c = 1% in chloroform
Sensitive	air sensitive
BRN	5879302

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	37/39-26-24/25
WGK Germany	3
F	10-23
Hazard Note	Irritant
HS Code	29349990

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Usage And Synthesis

Chemical Properties	White crystalline powder
Reactions	Chiral ligand used in the asymmetric reduction of highly substituted olefins. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole. Decarboxylative allylic alkylation.

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials

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