| Ethyl benzoylformate Basic information |
| Product Name: | Ethyl benzoylformate |
| Synonyms: | RARECHEM AL BI 0384;PHENYLETHYLGLYOXYLATE;PHENYLGLYOXYLIC ACID ETHYL ESTER;alpha-oxo-benzeneaceticaciethylester;Benzenaceticacid,-oxoethylester;Benzeneaceticacid,α-oxo-,ethylester;Ethyl oxophenylacetate;Ethyloxophenylacetate |
| CAS: | 1603-79-8 |
| MF: | C10H10O3 |
| MW: | 178.18 |
| EINECS: | 216-504-0 |
| Product Categories: | Pharmaceutical Intermediates;Aromatic Esters;Esters;Phenyls & Phenyl-Het;API intermediates;Phenyls & Phenyl-Het |
| Mol File: | 1603-79-8.mol |
| Ethyl benzoylformate Chemical Properties |
| Boiling point | 138-139 °C/18 mmHg (lit.) |
| density | 1.122 g/mL at 25 °C (lit.) |
| refractive index | 1.515-1.517 |
| Fp | 113 °C |
| storage temp. | Store below +30°C. |
| form | Liquid |
| Specific Gravity | 1.122 |
| color | Clear colorless to greenish |
| Water Solubility | Soluble in water 1143 mg/L @ 25°C . |
| Sensitive | Moisture Sensitive |
| CAS DataBase Reference | 1603-79-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8) |
| EPA Substance Registry System | Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8) |
| Safety Information |
| Hazard Codes | Xi |
| Safety Statements | 24/25 |
| WGK Germany | 3 |
| Hazard Note | Moisture Sensitive |
| TSCA | Yes |
| HazardClass | IRRITANT |
| HS Code | 29183000 |
| MSDS Information |
| Provider | Language |
|---|---|
| Ethyl phenylglyoxylate | English |
| ACROS | English |
| ALFA | English |
| Ethyl benzoylformate Usage And Synthesis |
| Chemical Properties | clear colorless to greenish liquid |
| Uses | Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts. |
| Application | Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position. |
| Definition | ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid. |
| Synthesis Reference(s) | Journal of the American Chemical Society, 82, p. 918, 1960The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7 |
| General Description | Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied. |
| Ethyl benzoylformate Preparation Products And Raw materials |
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