| 3-Bromo-2-(bromomethyl)propionic acid Basic information |
| Product Name: | 3-Bromo-2-(bromomethyl)propionic acid |
| Synonyms: | 3-BROMO-2-(BROMOMETHYL)PROPANOIC ACID;3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID;Propanoic acid, 3-bromo-2-(bromomethyl)-;BETA,BETA'-DIBROMOISOBUTYRIC ACID;bis(bromomethyl)acetic acid;β,β'-dibromoisobutyric acid;3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID (KG LEVEL);3-Bromo-2-(bromomethyl)propionic acid ,98% |
| CAS: | 41459-42-1 |
| MF: | C4H6Br2O2 |
| MW: | 245.9 |
| EINECS: | |
| Product Categories: | Building Blocks;C1 to C5;Carbonyl Compounds;Carboxylic Acids;Chemical Synthesis;Organic Building Blocks |
| Mol File: | 41459-42-1.mol |
| 3-Bromo-2-(bromomethyl)propionic acid Chemical Properties |
| Melting point | 98-101 °C(lit.) |
| Boiling point | 286.7±30.0 °C(Predicted) |
| density | 2.121±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Soluble in acetic acid. |
| form | Crystalline Powder |
| pka | 3.33±0.11(Predicted) |
| color | Off-white to brown |
| BRN | 1752505 |
| CAS DataBase Reference | 41459-42-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Propionic acid, 3-bromo-2-(bromomethyl)-(41459-42-1) |
| Safety Information |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 8 |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29159000 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| 3-Bromo-2-(bromomethyl)propionic acid Usage And Synthesis |
| Chemical Properties | off-white to brown crystalline powder |
| Uses | 3-Bromo-2-(bromomethyl)propionic acid acts as an organic building block for the preparation of beta-substituted acrylates. It is used in the preparation of t-butyl 2-(phenylthiomethyl) propenoate, t-butyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl-sulfinylmethyl)propenoate. Further, it plays an important role in the synthesis of beta-lactams by cyclization of the corresponding amide. |
| General Description | 3-Bromo-2-(bromomethyl)propionic acid reacts with alkaline arsenite to yield (RS)-3-arsono-2-(hydroxymethyl)propionic acid. |
| 3-Bromo-2-(bromomethyl)propionic acid Preparation Products And Raw materials |
| Raw materials | Diethyl ether-->Sulfuric acid-->Toluene-->Nitric acid-->Sodium sulfate-->Formaldehyde-->Hydrogen bromide-->Diethyl malonate-->Ammonium sulfate-->Diisopropyl ether-->Potassium bicarbonate-->Diethyl bis(hydroxymethyl)malonate |
| Preparation Products | ALPHA-BROMOCROTONICACID-->2-(BROMOMETHYL)ACRYLIC ACID |
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