(R)-(+)-1-Phenylethyl isocyanate Basic information |
Product Name: | (R)-(+)-1-Phenylethyl isocyanate |
Synonyms: | ISOCYANIC ACID (R)-(+)-1-PHENYLETHYL ESTER;ISOCYANIC ACID (R)-(+)-ALPHA-METHYLBENZYL ESTER;(R)-(+)-1-PHENYLETHYL ISOCYANATE;(R)-1-PHENYLETHYLISOCYANATE;(R)-(+)-A-METHYLBENZYL ISOCYANATE;(R)-(+)-ALPHA-METHYLBENZYL ISOCYANATE;(R)(+)-ALPHA-PHENETHYL ISOCYANATE;(R) METHYL BENZYLISOCYANATE |
CAS: | 33375-06-3 |
MF: | C9H9NO |
MW: | 147.17 |
EINECS: | 251-485-2 |
Product Categories: | chiral;Isocyanates (Chiral);Analytical Chemistry;Chiral Building Blocks;e.e. / Absolute Configuration Determination (NMR);e.e. Determination (HPLC Labeling Reagents);Enantiomer Excess & Absolute Configuration Determination;for Resolution of Alcohols & Thiols;for Resolution of Bases;Optical Resolution;Synthetic Organic Chemistry |
Mol File: | 33375-06-3.mol |
(R)-(+)-1-Phenylethyl isocyanate Chemical Properties |
Boiling point | 55-56 °C2.5 mm Hg(lit.) |
alpha | 10 º (NEAT) |
density | 1.045 g/mL at 20 °C(lit.) |
refractive index | n |
Fp | 150 °F |
storage temp. | 2-8°C |
form | Liquid |
color | Clear colorless to pale yellow |
optical activity | [α]20/D +10°, neat |
Water Solubility | Decomposition |
Sensitive | Moisture Sensitive |
BRN | 3196930 |
InChIKey | JJSCUXAFAJEQGB-UHFFFAOYSA-N |
CAS DataBase Reference | 33375-06-3(CAS DataBase Reference) |
Safety Information |
Hazard Codes | Xn,T+,T |
Risk Statements | 36/37/38-42-26-23/24/25-23 |
Safety Statements | 23-26-36-45-24/25-38-36/37/39-7/9 |
RIDADR | UN 2206 6.1/PG 2 |
WGK Germany | 3 |
F | 3-10-21 |
HazardClass | 6.1 |
PackingGroup | III |
HS Code | 29291090 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ACROS | English |
ALFA | English |
(R)-(+)-1-Phenylethyl isocyanate Usage And Synthesis |
Chemical Properties | Colorless to light yellow liqui |
Uses | (R)-1-phenylethyl isocyanate is used in the derivatisation of alcohols, thiocarbamates and hydroxy fatty acids. (R)-1-phenylethyl isocyanate moderately inhibited both BP-DNA adducts. |
General Description | (R)-(+)-a-Methylbenzyl isocyanate [(R)-(+)-MBIC] is a derivatizing agent. |
Purification Methods | Purify the isocyanates by fractional distillation under a vacuum. With ammonia |
(R)-(+)-1-Phenylethyl isocyanate Preparation Products And Raw materials |
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