4-FLUOROPHENYLMAGNESIUM BROMIDE
4-FLUOROPHENYLMAGNESIUM BROMIDE
  • CAS No.:352-13-6
Other grades of this product :
4-FLUOROPHENYLMAGNESIUM BROMIDE Basic information
Product Name:4-FLUOROPHENYLMAGNESIUM BROMIDE
Synonyms:4-FLUOROPHENYLMAGNESIUM BROMIDE;4-FLUOROPHENYLMAGNESIUM BROMIDE, 2M IN DIETHYL ETHER;4-FLUOROPHENYLMAGNESIUM BROMIDE, 2.0M SO LUTION IN DIETHYL ETHER;4-FLUOROPHENYLMAGNESIUM BROMIDE SOL., ~2 .0 M IN DIETHYL ET;4-FLUOROPHENYLMAGNESIUM BROMIDE, 1.0M SO LUTION IN TETRAHYDROFURAN;4-FLUOROPHENYLMAGNESIUM BROMIDE SOL., ~1 M IN THF;4-Fluorophenylmagnesium Bromide 1.0 M In Tetrahydrofuran;4-Fluorophenylmagnesium Bromide 2.0 M In Diethyl Ether
CAS:352-13-6
MF:C6H4BrFMg
MW:199.31
EINECS:627-087-3
Product Categories:Grignard Reagents;Aryl;Organometallic Reagents;Grignard Reagent
Mol File:352-13-6.mol
4-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties
Melting point 5 °C
Boiling point 66°C
density 1.043 g/mL at 25 °C
Fp −40 °F
storage temp. Flammables + water-Freezer (-20°C)e area
form Solution
color Clear yellow to red-brown
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
BRN 636802
InChIKeyQYBFFRXNNFXREA-UHFFFAOYSA-M
CAS DataBase Reference352-13-6
EPA Substance Registry SystemMagnesium, bromo(4-fluorophenyl)- (352-13-6)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-22-34-66-67-11-40-37-19
Safety Statements 16-26-36/37/39-43-45-7/8-33-8-7
RIDADR UN 2924 3/PG 2
WGK Germany 1
10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
4-FLUOROPHENYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical Propertiesclear yellow to red-brown solution
Uses4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.
Uses4-Fluorophenylmagnesium bromide solution (Grignard reagent) can be used as a reagent in the synthesis of:
  • Useful key intermediate in the synthesis of paroxetine.
  • Arylsulfides via cross-coupling reaction with thiols.
  • 4-Arylmethyl-1-phenylpyrazole and 4-aryloxy-1-phenylpyrazole derivatives as androgen receptor antagonists.
  • Grignard intermediate for preparing aprepitant.

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