| (R)-(+)-2-Methyl-2-propanesulfinamide Basic information |
| Product Name: | (R)-(+)-2-Methyl-2-propanesulfinamide |
| Synonyms: | R- tert butyl sulfenaMide;(R)-(+)-TERT-BUTANESULFINAMIDE;(R)-TERT-BUTANESULFINAMIDE;(R)-(+)-T-BUTANESULFINAMIDE;(R)-(+)-T-BUTYLMETHYLSULFINAMIDE;(R)-(+)-T-BUTYLSULFINAMIDE;(R)-(+)-TERT-BUTYLSULFINAMIDE;(R)-(+)-TERT-BUTYL SULPHINAMIDE |
| CAS: | 196929-78-9 |
| MF: | C4H11NOS |
| MW: | 121.2 |
| EINECS: | 676-338-3 |
| Product Categories: | organosulfur compound;chiral;blocks;BuildingBlocks;Heterocyclic Compounds;CHIRAL COMPOUNDS;Sulfonamides;Asymmetric Synthesis;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;CHIRAL CHEMICALS;Sulfur Compounds;Chiral Compound;Amines;Chiral Reagents;Intermediates;Sulfur & Selenium Compounds;Asymmetric Synthesis;Chiral Auxiliaries;Sulfur-Based |
| Mol File: | 196929-78-9.mol |
| (R)-(+)-2-Methyl-2-propanesulfinamide Chemical Properties |
| Melting point | 103-107 °C(lit.) |
| alpha | 4 º (c=1, CHCl3 + amylenes) |
| Boiling point | 220.0±23.0 °C(Predicted) |
| density | 0.903 g/mL at 25 °C |
| refractive index | 4 ° (C=1, CHCl3) |
| Fp | -17℃ |
| storage temp. | 2-8°C |
| solubility | Soluble in chloroform, methanol, tetrahydrofuran, dichloromethane, dimethyl sulfoxide and most organic solvents. |
| form | Powder |
| pka | 10.11±0.50(Predicted) |
| color | White, light pink, light yellow to brown |
| optical activity | [α]22/D +1.0°, c = 0.5% in chloroform |
| Stability: | store cold |
| InChIKey | CESUXLKAADQNTB-SSDOTTSWSA-N |
| CAS DataBase Reference | 196929-78-9(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xi,Xn,F |
| Risk Statements | 11-19-36/37-40-36/37/38 |
| Safety Statements | 22-24/25-36/37-26-16-36/37/39 |
| RIDADR | UN 2056 3 / PGII |
| WGK Germany | 3 |
| Hazard Note | Irritant/Keep Cold |
| TSCA | No |
| HS Code | 29309090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| (R)-(+)-2-Methyl-2-propanesulfinamide Usage And Synthesis |
| Chemical Properties | (R)-(+)-2-Methyl-2-propanesulfinamide is white to light yellow crystal powde |
| Uses | suzuki reaction, useful reagent for synthesizing chiral amines. |
| Uses | (R)-(+)-2-Methyl-2-propanesulfinamide is a chiral ligand, which is used in pharmaceutical compositions. Further, it is used in the preparation of beta-chloro sulfinamides in the synthesis of chiral azridines. It is involved in the preparation of organocatalyst for enantioselective reduction of imines. It serves as a reagent for synthesizing chiral amines. In addition to this, it is converted into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones which undergoes iridium-catalyzed asymmetric hydrogenation of olefins. |
| Uses | Chiral ligand used in pharmaceutical compositions |
| (R)-(+)-2-Methyl-2-propanesulfinamide Preparation Products And Raw materials |
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