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| Methyl nitroacetate Basic information |
| Methyl nitroacetate Chemical Properties |
| Boiling point | 195-198 °C (lit.) | | density | 1.294 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.425(lit.) | | Fp | 221 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Miscible with ethanol, ether and most organic solvents. | | pka | 5.73±0.29(Predicted) | | form | clear liquid | | color | Colorless to Light yellow | | Sensitive | Light Sensitive | | BRN | 1758670 | | InChIKey | ALBSWLMUHHZLLR-UHFFFAOYSA-N | | CAS DataBase Reference | 2483-57-0(CAS DataBase Reference) | | NIST Chemistry Reference | Acetic acid, nitro-, methyl ester(2483-57-0) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-37/39 | | WGK Germany | 2 | | RTECS | AJ1093000 | | F | 8 | | HS Code | 29161995 |
| Methyl nitroacetate Usage And Synthesis |
| Chemical Properties | clear yellow liquid | | Uses | Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606 |
| Methyl nitroacetate Preparation Products And Raw materials |
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