N,N-Dimethyltrimethylsilylamine
N,N-Dimethyltrimethylsilylamine
  • CAS No.:2083-91-2
Other grades of this product :
N,N-Dimethyltrimethylsilylamine Basic information
Product Name:N,N-Dimethyltrimethylsilylamine
Synonyms:N,N-DIMETHYLAMINOTRIMETHYLSILANE;N,N-DIMETHYLAMINOTRIMETHYLSILANE TMSDMA;N,N-DIMETHYLTRIMETHYLSILYLAMINE;N-TRIMETHYLSILYDIMETHYLAMINE;N-(TRIMETHYLSILYL)DIMETHYLAMINE;DIMETHYLAMINOTRIMETHYLSILAN;(DIMETHYLAMINO)TRIMETHYLSILANE;TMSDMA
CAS:2083-91-2
MF:C5H15NSi
MW:117.26
EINECS:218-222-3
Product Categories:Derivatization Reagents GC;Reagents for Silylation;Silylation Reagents;Analytical Reagents;Analytical/Chromatography;Building Blocks;Aminosilanes;Synthetic Organic Chemistry;Trimethylsilylation (GC Derivatizing Reagents);Chemical Synthesis;Derivatization Reagents;Nitrogen Compounds;Organic Building Blocks;Protected Amines;Analytical Chemistry;GC Derivatizing Reagents;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Silylation (GC Derivatizing Reagents);Si-N Compounds
Mol File:2083-91-2.mol
N,N-Dimethyltrimethylsilylamine Chemical Properties
Melting point <0°C
Boiling point 84 °C (lit.)
density 0.732 g/mL at 25 °C (lit.)
refractive index n20/D 1.397(lit.)
Fp −3 °F
storage temp. Flammables area
pka10.77±0.70(Predicted)
form clear liquid
color Colorless to Light yellow
Specific Gravity0.74
Water Solubility Decomposition
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 1731861
CAS DataBase Reference2083-91-2(CAS DataBase Reference)
NIST Chemistry ReferenceDimethylamino(trimethyl)silane(2083-91-2)
EPA Substance Registry SystemSilanamine, pentamethyl- (2083-91-2)
Safety Information
Hazard Codes F,C
Risk Statements 11-34
Safety Statements 16-26-36/37/39-45
RIDADR UN 2733 3/PG 2
WGK Germany 3
1-10
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
N,N-Dimethyltrimethylsilylamine Usage And Synthesis
Chemical Propertiesclear colorless to pale yellow liquid
UsesN,N-Dimethyltrimethylsilylamine was used in the synthesis of phosphoramidite. It was also employed as a reagent in the preparation of iminium salts and amides as well as for the silylation of polymers. A combination of N-(trimethylsilyl)dimethylamine and MeI was also effective to give p-methylbenzoic acid with a 85% yield based on 90% conversion from the corresponding Me ester. DETA has been treated with N-(trimethylsilyl)-dimethylamine to yield mono-, di- and tri- silylated derivatives

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