| Tetrabutylammonium hexafluorophosphate Basic information |
| Product Name: | Tetrabutylammonium hexafluorophosphate |
| Synonyms: | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-);tetrabutylammonium-hexafluorphosophat;ammonium hexafL;uorophosphate;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE, ELECTROCHEM. GRADE;TETRA-N-BUTYLAMMONIUM HEXAFLUOROPHOSPHATE;Tetrabutylammoniumhexafluorophosphate,98% |
| CAS: | 3109-63-5 |
| MF: | C16H36F6NP |
| MW: | 387.43 |
| EINECS: | 221-472-6 |
| Product Categories: | metal fluorophosphate complex;Ammonium Polyhalides, etc. (Quaternary);Quaternary Ammonium Compounds;Ammonium SaltsAnalytical Reagents;Electrochemistry;Greener Alternatives: Catalysis;Phase Transfer Catalysts;Supporting Electrolytes for Electrochemistry;Ammonium Salts |
| Mol File: | 3109-63-5.mol |
| Tetrabutylammonium hexafluorophosphate Chemical Properties |
| Melting point | 244-246 °C (lit.) |
| Boiling point | 242-246 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | acetonitrile: 0.1 g/mL, clear, colorless |
| form | Crystalline Powder and/or Chunks |
| color | White to off-white |
| Sensitive | Hygroscopic |
| BRN | 4056584 |
| CAS DataBase Reference | 3109-63-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Tetrabutylammonium hexafluorophosphate(3109-63-5) |
| EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (3109-63-5) |
| Safety Information |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-22 |
| Safety Statements | 26-36/37 |
| RIDADR | 1759 |
| WGK Germany | 3 |
| Hazard Note | Irritant/Hygroscopic |
| TSCA | Yes |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29239000 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Tetrabutylammonium hexafluorophosphate Usage And Synthesis |
| Chemical Properties | off-white powder |
| Uses | Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides. |
| Uses | Tetrabutylammonium hexafluorophosphate (TBAPF6) or TBAHP can be used:
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| General Description | Visit our Sensor Applications portal to learn more. |
| Purification Methods | Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.] |
| Tetrabutylammonium hexafluorophosphate Preparation Products And Raw materials |
| Raw materials | Water-->Tetrabutylammonium bromide-->Potassium hexafluorophosphate-->Tetrabutylammonium hydroxide-->Diethyl phosphite-->Tetrabutyl ammonium chloride |
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