Tetrabutylammonium hexafluorophosphate Basic information |
Product Name: | Tetrabutylammonium hexafluorophosphate |
Synonyms: | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-);tetrabutylammonium-hexafluorphosophat;ammonium hexafL;uorophosphate;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE, ELECTROCHEM. GRADE;TETRA-N-BUTYLAMMONIUM HEXAFLUOROPHOSPHATE;Tetrabutylammoniumhexafluorophosphate,98% |
CAS: | 3109-63-5 |
MF: | C16H36F6NP |
MW: | 387.43 |
EINECS: | 221-472-6 |
Product Categories: | metal fluorophosphate complex;Ammonium Polyhalides, etc. (Quaternary);Quaternary Ammonium Compounds;Ammonium SaltsAnalytical Reagents;Electrochemistry;Greener Alternatives: Catalysis;Phase Transfer Catalysts;Supporting Electrolytes for Electrochemistry;Ammonium Salts |
Mol File: | 3109-63-5.mol |
Tetrabutylammonium hexafluorophosphate Chemical Properties |
Melting point | 244-246 °C (lit.) |
Boiling point | 242-246 °C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | acetonitrile: 0.1 g/mL, clear, colorless |
form | Crystalline Powder and/or Chunks |
color | White to off-white |
Sensitive | Hygroscopic |
BRN | 4056584 |
CAS DataBase Reference | 3109-63-5(CAS DataBase Reference) |
NIST Chemistry Reference | Tetrabutylammonium hexafluorophosphate(3109-63-5) |
EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (3109-63-5) |
Safety Information |
Hazard Codes | Xi,Xn |
Risk Statements | 36/37/38-22 |
Safety Statements | 26-36/37 |
RIDADR | 1759 |
WGK Germany | 3 |
Hazard Note | Irritant/Hygroscopic |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | III |
HS Code | 29239000 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Tetrabutylammonium hexafluorophosphate Usage And Synthesis |
Chemical Properties | off-white powder |
Uses | Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides. |
Uses | Tetrabutylammonium hexafluorophosphate (TBAPF6) or TBAHP can be used:
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General Description | Visit our Sensor Applications portal to learn more. |
Purification Methods | Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.] |
Tetrabutylammonium hexafluorophosphate Preparation Products And Raw materials |
Raw materials | Water-->Tetrabutylammonium bromide-->Potassium hexafluorophosphate-->Tetrabutylammonium hydroxide-->Diethyl phosphite-->Tetrabutyl ammonium chloride |
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