| Dichloro(1,5-cyclooctadiene)palladium(II) Basic information |
| Product Name: | Dichloro(1,5-cyclooctadiene)palladium(II) |
| Synonyms: | dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu;(1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE;1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE;DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADATE (II);DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADIUM(II);DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PALLADIUM (II);DICHLORO(1,5-CYCLOOCTYLDIENE)PALLADIUM(II);DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(II) |
| CAS: | 12107-56-1 |
| MF: | C8H12Cl2Pd |
| MW: | 285.51 |
| EINECS: | 235-161-8 |
| Product Categories: | chemical reaction,pharm,electronic,materials;organometallic complexes;Catalysts for Organic Synthesis;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Pd |
| Mol File: | 12107-56-1.mol |
| Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties |
| Melting point | 210 °C (dec.) (lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in dichloromethane |
| form | crystal |
| color | yellow |
| Water Solubility | insoluble |
| Sensitive | Hygroscopic |
| InChIKey | NEKYMUKEOUDFPP-XRGHXPOKSA-L |
| CAS DataBase Reference | 12107-56-1(CAS DataBase Reference) |
| EPA Substance Registry System | Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 28439000 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Dichloro(1,5-cyclooctadiene)palladium(II) Usage And Synthesis |
| Chemical Properties | yellow |
| Uses | Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene. |
| Uses | Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions. |
| Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials |
| Raw materials | Toluene-->Acetonitrile-->Palladium chloride-->1,5-Cyclooctadiene |
Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.
日本语
한국어
Français
Deutsch
España
Türkiye