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Allyltriphenylphosphonium bromide Basic information |
Allyltriphenylphosphonium bromide Chemical Properties |
Melting point | 222-225 °C (lit.) | storage temp. | Sealed in dry,Room Temperature | form | Powder | color | White | Water Solubility | decomposes | Sensitive | Hygroscopic | BRN | 3579053 | InChIKey | FWYKRJUVEOBFGH-UHFFFAOYSA-M | CAS DataBase Reference | 1560-54-9(CAS DataBase Reference) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-37/39 | WGK Germany | 3 | RTECS | TA1843000 | HS Code | 29310095 |
Allyltriphenylphosphonium bromide Usage And Synthesis |
Chemical Properties | white crystalline powder | Uses | Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes. | Preparation | Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene. | Application | Reactant for:Preparation of a diol and carbamate chemistry library for common functional groupsRegioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienesAlkene addition of frustrated Lewis pairsOlefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenesWittig olefination of aldehydes for preparation of conjugated dienesTandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienesReaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.Methyl 3-(buta-1,3-dienyl)benzoate1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene1-(Buta-1,3-dienyl)-2-chlorobenzene1-Bromo-4-(buta-1,3-dienyl)benzeneButa-1,3-dienylbenzene |
Allyltriphenylphosphonium bromide Preparation Products And Raw materials |
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