4-Vinylcyclohexene dioxide
4-Vinylcyclohexene dioxide
  • CAS No.:106-87-6
Other grades of this product :
4-Vinylcyclohexene dioxide Basic information
Product Name:4-Vinylcyclohexene dioxide
Synonyms:1-EPOXYETHYL-3.4-EPOXYCYCLOHEXANE;3-(epoxyethyl)-7-oxabicyclo(4.1.0)heptan;3-epoxyethyl-7-oxabicycloheptane;3-oxiranyl-7-oxabicyclo(4.1.0)heptan;3-oxiranyl-7-oxabicyclo(4.1.0)heptane;3-oxiranyl-7-oxabicyclo(4.1.0)heptene;3-oxiranyl-7-oxabicyclo[4.1.0]heptan;Vinylcyclohexene dioxid
CAS:106-87-6
MF:C8H12O2
MW:140.18
EINECS:203-437-7
Product Categories:
Mol File:106-87-6.mol
4-Vinylcyclohexene dioxide Chemical Properties
Melting point -55°C
Boiling point 230-232 °C(lit.)
density 1.094 g/mL at 25 °C(lit.)
refractive index n20/D 1.477(lit.)
Fp 225 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Colorless or pale yellow liquid
Water Solubility 154.7g/L(20 ºC)
BRN 106071
Stability:Stable. Combustible. Incompatible with strong oxidizing agents, alcohols, amines and other compounds containg an active hydrogen. Hydrolyzes slowly in water.
CAS DataBase Reference106-87-6(CAS DataBase Reference)
IARC2B (Vol. Sup 7, 60) 1994
EPA Substance Registry System4-Vinylcyclohexene diepoxide (106-87-6)
Safety Information
Hazard Codes T
Risk Statements 23/24/25-68/20/21/22-68
Safety Statements 23-24-45
RIDADR UN 2810 6.1/PG 3
WGK Germany 1
RTECS RN8640000
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data106-87-6(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Vinylcyclohexene dioxide Usage And Synthesis
Chemical Propertiescolourless liquid. Combustible.
Chemical PropertiesVinyl cyclohexene dioxide is a colorless liquid
UsesVinylcyclohexene dioxide (VCD) is used to study toxicity as an ovotoxin,and it's also used to understand its mechanisms of toxicity towards ovarian follicles and effects on epithelial differentiation.
UsesAs a chemical intermediate and as a reactive diluent for diepoxides and epoxy resins.
UsesVinylcyclohexene dioxide (VCD) may be used to study and understand its effect on ovarian follicles and effects on epithelial differentiation.
Production MethodsVCHD is manufactured by epoxidation of 4-vinylcyclohexene with peroxyacetic acid .
DefinitionChEBI: The diepoxide of 4-vinylcyclohexene.
General DescriptionClear colorless liquid. Sets to glass at -67°F. Faint olefinic odor.
Air & Water ReactionsWater soluble. Hydrolyzes slowly in water.
Reactivity Profile4-VINYLCYCLOHEXENE DIOXIDE reacts with active hydrogen compounds (such as alcohols and amines). . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
HazardToxic by ingestion and skin absorption, strong irritant to skin and tissue. Female and male reproductive damage. Possible carcinogen.
Health HazardVinyl cyclohexene dioxide (VCD) is an irritant to the skin, eyes, and respiratory system. It is ovotoxic and carcinogenic in experimental animals.
Safety ProfileConfirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by unspecified route. Moderately toxic by ingestion and skin contact. Mildly toxic by inhalation. Experimental reproductive effects. Mutation data reported. A severe skin irritant.Combustible when exposed to heat or flame. To fight fire, use water, foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential ExposureThis material is used as a monomer in the production of epoxy resins for coatings and adhesives; as a chemical intermediate and as a reactive diluent.
Carcinogenicity4-Vinyl-1-cyclohexene diepoxide is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals.
ShippingUN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesWhen heated or in contact with catalysts, epoxides may cause violent polymerization. Epoxides are incompatible with reducing agents and oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May react, possibly violently, with water in the presence of acid and other catalysts. Reacts with alcohols, amines and other active hydrogen compounds. Slowly hydrolyzes in water.
Waste DisposalConcentrated waste containing no peroxides: discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxides: perforation of a container of the waste from a safe distance followed by open burning.

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