| LITHIUM TRIMETHYLSILANOLATE Basic information |
| Product Name: | LITHIUM TRIMETHYLSILANOLATE |
| Synonyms: | trimethyl-silanolithiumderivative;trimethylsilanollithiumderiv.;LITHIUM TRIMETHYLSILANOLATE, 20% in toluene;LITHIUM TRIMETHYLSILANOLATE, 1.0M SOLUTI ON IN DICHLOROMETHANE;Lithiumtrimethylsilanolatepure;lithium trimethylsilanolate solution;LITHIUM TRIMETHYLSILANOLATE;Trimethylsiloxylithium |
| CAS: | 2004-14-0 |
| MF: | C3H9LiOSi |
| MW: | 96.13 |
| EINECS: | |
| Product Categories: | Chemical Synthesis;Organic Bases;Synthetic Reagents |
| Mol File: | 2004-14-0.mol |
| LITHIUM TRIMETHYLSILANOLATE Chemical Properties |
| Boiling point | 40 °C |
| density | 1.278 g/mL at 25 °C |
| vapor pressure | 24.12 psi ( 55 °C) |
| Fp | 145 °F |
| Specific Gravity | 0.876 |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 3686900 |
| Safety Information |
| Hazard Codes | C,T |
| Risk Statements | 34-40-23/24/25 |
| Safety Statements | 26-28-36/37/39-45-27-16 |
| RIDADR | UN 3267 8/PG 2 |
| WGK Germany | 3 |
| RTECS | VV7175000 |
| F | 10-21 |
| TSCA | No |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29310099 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| LITHIUM TRIMETHYLSILANOLATE Usage And Synthesis |
| Purification Methods | Wash it with Et2O and pet ether. It sublimes at 180o/1mm as fine transparent needles. [Tatlock & Rochnow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.] Suspected CARCINOGEN. |
| LITHIUM TRIMETHYLSILANOLATE Preparation Products And Raw materials |
| Preparation Products | N-(Trimethylsilyl)-2,2-dimethylpropane-1-imine-->1-Phospha-1-butyne, 3,3-dimethyl--->1-Butene, 1-bromo-3-methyl--->1-(1,1 -Dimethylethoxy)butane-->Hydrogen-->1-BUTENE |
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