ETHYL 2-(BROMOMETHYL)ACRYLATE
ETHYL 2-(BROMOMETHYL)ACRYLATE
  • CAS No.:17435-72-2
Other grades of this product :
ETHYL 2-(BROMOMETHYL)ACRYLATE Basic information
Product Name:ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms:Ethyl2-(Bromomethyl)acrvlate;3-bromo-2-methyl-2-propenoic acid ethyl ester;2-Propenoic acid, 2-(bromomethyl)-, ethyl ester;2-(Bromomethyl)-2-propenoic Acid Ethyl Ester;2-Carbethoxyallyl Bromide;Ethyl 2-(Bromomethyl)-2-propenoate;Ethyl 3-Bromo-2-(methylene)propanoate;Ethyl Bromomethacrylate
CAS:17435-72-2
MF:C6H9BrO2
MW:193.04
EINECS:628-033-1
Product Categories:Benzothiophenes ,Thiophenes;Aliphatics;AcrylateCarbonyl Compounds;Acrylic Monomers;C6 to C7;Esters;All Aliphatics;Monomers
Mol File:17435-72-2.mol
ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties
Melting point 134-136℃
Boiling point 38 °C/0.8 mmHg (lit.)
density 1.398 g/mL at 25 °C (lit.)
refractive index n20/D 1.479(lit.)
Fp 178 °F
storage temp. -20°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Liquid
color Colorless to pale yellow
BRN 970108
InChIKeyMTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference17435-72-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 2810 6.1 / PGII
WGK Germany 3
10-19-23
HS Code 29161900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ETHYL 2-(BROMOMETHYL)ACRYLATE Usage And Synthesis
Chemical PropertiesColourless Oil
UsesETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.
UsesIt can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.
General DescriptionEthyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.
Purification MethodsIf it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

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