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| Bromocyclohexane Basic information |
| Bromocyclohexane Chemical Properties |
| Melting point | -57°C | | Boiling point | 166-167 °C (lit.) | | density | 1.324 g/mL at 25 °C (lit.) | | vapor density | 5.62 (vs air) | | refractive index | n20/D 1.495(lit.) | | Fp | 145 °F | | storage temp. | Sealed in dry,Room Temperature | | solubility | H2O: insoluble | | form | Liquid | | color | Clear colorless to light yellow | | Specific Gravity | approximate 1.33 (20℃) | | Odor | Unpleasant Odor | | Water Solubility | insoluble | | Sensitive | Air & Light Sensitive | | Merck | 14,2730 | | BRN | 1098373 | | Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. | | InChIKey | AQNQQHJNRPDOQV-UHFFFAOYSA-N | | CAS DataBase Reference | 108-85-0(CAS DataBase Reference) | | NIST Chemistry Reference | Cyclohexane, bromo-(108-85-0) | | EPA Substance Registry System | Cyclohexane, bromo- (108-85-0) |
| Bromocyclohexane Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy. | | Synthesis Reference(s) | Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020 | | General Description | Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon. | | Purification Methods | Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.] |
| Bromocyclohexane Preparation Products And Raw materials |
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