(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP
  • CAS No.:917377-74-3
Other grades of this product :

(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP Basic information
Uses
Product Name:(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP
Synonyms:(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP;1,1'-[(1R)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-DIPHENYLPHOSPHINE];1,1'-[(1R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-diphenylphosphine],99%e.e.;(R)-(+)-7,7′-Bis(diphenylphosphino)-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;Phosphine, 1,1'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-diphenyl- (9CI);(R)-SDP,(R)-7,7′-bis(diphenylphosphino)-1,1′-spirobiindane;917377-74-3
CAS:917377-74-3
MF:C41H34P2
MW:588.66
EINECS:
Product Categories:BINAP Series;Chiral Phosphine;Chiral Spiro Ligand
Mol File:917377-74-3.mol
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP Chemical Properties
Melting point 200-202°C
alpha +207° (c 0.5, CH2Cl2)
Boiling point 690.2±55.0 °C(Predicted)
storage temp. -20°C
form solid
color white
optical activity[α]22/D +184°, c = 1 in chloroform
Sensitive air sensitive
Safety Information
WGK Germany 3
MSDS Information
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP Usage And Synthesis
Uses
  1. Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.

  2. Ligands used for palladium-catalyzed asymmetric allylic alkylations. 

 
Chemical Properties(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP is White to light yellow solid
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP Preparation Products And Raw materials

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