2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
  • CAS No.:7428-60-6
Other grades of this product :
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Basic information
Product Name:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
Synonyms:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-;Tris(trimethylsilyl)silanol;Tris(trimethylsilyl)silanol >=95%
CAS:7428-60-6
MF:C9H28OSi4
MW:264.66
EINECS:
Product Categories:
Mol File:7428-60-6.mol
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Chemical Properties
Boiling point 235.1±23.0 °C(Predicted)
density 0.833±0.06 g/cm3(Predicted)
pka15.57±0.53(Predicted)
Safety Information
MSDS Information
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Usage And Synthesis
UsesUnder a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Preparation Products And Raw materials
Raw materialsTrisilane, 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)--->TETRAKIS(TRIMETHYLSILYL)SILANE-->TRIS(TRIMETHYLSILYL)SILANE-->2-Bromopropane
Preparation ProductsCHLOROTRIS(TRIMETHYLSILYL)SILANE-->MESITYL OXIDE

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