CIS-4-HEPTENAL
CIS-4-HEPTENAL
  • CAS No.:6728-31-0
Other grades of this product :
CIS-4-HEPTENAL Basic information
Product Name:CIS-4-HEPTENAL
Synonyms:FEMA 3289;CIS-4-HEPTEN-1-AL;CIS-4-HEPTENAL;C4 HEPTENAL;TIMTEC-BB SBB006608;(4Z)-4-Heptenal;(Z)-4-Hepten-1-al;(z)-4-heptena
CAS:6728-31-0
MF:C7H12O
MW:112.17
EINECS:229-779-7
Product Categories:Alpha Sort;E-L;Alphabetical Listings;Flavors and Fragrances;G-H;Volatiles/ Semivolatiles
Mol File:6728-31-0.mol
CIS-4-HEPTENAL Chemical Properties
Melting point -53.35°C (estimate)
Boiling point 60 °C25 mm Hg(lit.)
density 0.850 g/mL at 20 °C(lit.)
refractive index n20/D 1.434
FEMA 3289 | 4-HEPTENAL
Fp 105 °F
storage temp. 0-6°C
form Liquid
color Clear colorless to light yellow
JECFA Number320
BRN 1902614
CAS DataBase Reference6728-31-0(CAS DataBase Reference)
EPA Substance Registry System4-Heptenal, (4Z)- (6728-31-0)
Safety Information
Risk Statements 10
Safety Statements 16-24/25
RIDADR UN 1989 3/PG 3
WGK Germany 3
10-23
HazardClass 3
PackingGroup III
HS Code 29121900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
CIS-4-HEPTENAL Usage And Synthesis
Descriptioncis-4-Heptenal has an odor reminiscent of heptaldehyde. It is suggestive of fried fats on dilution. It is used to impart a fried, buttery flavor. It is prepared from Hemiptera insects (trans-form); from pen-ten-l-en-3-ol converted to the corresponding vinyl ether which undergoes a Claisen rearrangement to 4-heptenal (transform).
Chemical Propertiescis-4-Heptenal has an odor reminiscent of heptaldehyde The odor is suggestive of fried fats on dilution It is used to impart a fried, buttery favor.
Chemical Propertiesclear colorless to light yellow liquid
Chemical Properties(Z)-4-Heptenal is a widespread volatile trace constituent of food flavors. It is a colorless, oily liquidwith a powerful, fatty, somewhat fishy, and, in high dilution, creamy odor. It can be prepared by several ways, for example, by starting from (Z)-3-hexenol. (Z)-4-Heptenal is used in cream, butter, and fat flavors.
OccurrenceReported found as a constitutent in butterfat, microbial fermented tea and black Hemiptera bugs
PreparationFrom Hemiptera bugs (trans-form); from penten-1-en-3-ol converted to the corresponding vinyl ether, which undergoes a Claisen rearrangement to 4-heptenal (trans-form).
Aroma threshold valuesDetection: 0.4 ppb.
CIS-4-HEPTENAL Preparation Products And Raw materials
Raw materialsAmmonia-->Bromoethane-->Acetal

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