(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
  • CAS No.:65283-60-5
Other grades of this product :
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Basic information
Reactions
Product Name:(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
Synonyms:6'-DIBROMO-1,1'-BI-2-NAPHTHOL;(+/-)-6,6'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL;(+/-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL;6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL;(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol,min.98%;(R)-(-)-6,6''-DIBROMO-1,1''-BI-2-NAPHTOL;AURORA KA-7214;(S)-(+)-6'-DIBROMO-1,1'-BI-2-NAPHTHOL
CAS:65283-60-5
MF:C20H12Br2O2
MW:444.12
EINECS:
Product Categories:BINOL Series;Chiral Oxygen;Chiral Compound;BINOLs;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;chiral;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:65283-60-5.mol
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Chemical Properties
Melting point 195-199 °C(lit.)
Boiling point 546.2±45.0 °C(Predicted)
alpha -48 º (c=1.8, THF)
density 1.5428 (rough estimate)
refractive index 1.4947 (estimate)
storage temp. Inert atmosphere,Room Temperature
Water Solubility Insoluble in water
pka7.78±0.50(Predicted)
form powder to crystal
color White to Light yellow to Light orange
optical activity[α]20/D 49°, c = 1.8 in acetic acid
CAS DataBase Reference65283-60-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
WGK Germany 3
HS Code 29081990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Usage And Synthesis
Reactions
  1. Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.
  2. Ligand used for titanium-catalyzed enantioselective Friedel-Crafts reactions. 
Chemical Propertieswhite to light yellow crystal powde
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Preparation Products And Raw materials
Raw materialsEthyl acetate-->Tetrahydrofuran-->Dichloromethane-->Government regulation-->(R)-(+)-1,1'-Bi-2-naphthol-->(S)-6,6'-dibroMo-2,2'-dihydroxy-1,1'-binaphthyl-->6-Bromo-2-naphthol
Preparation ProductsDINAPHTHO[1,2-B:1',2'-D]FURAN

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