4,4'-DIFLUOROBENZIL
4,4'-DIFLUOROBENZIL
  • CAS No.:579-39-5
Other grades of this product :
4,4'-DIFLUOROBENZIL Basic information
Product Name:4,4'-DIFLUOROBENZIL
Synonyms:1,2-Bis(4-fluorophenyl)-1,2-ethanedione;4,4'-DIFLUOROBENZIL;4,4'-DIFLUOROBIBENZOYL;4,4'-DIFLUORODIBENZOYL;4,4'-FLUOROBENZIL;BIS(P-FLUOROPHENYL)ETHANEDIONE;4,4'-Difluorobenzil,99%;Ethanedione, bis(4-fluorophenyl)-
CAS:579-39-5
MF:C14H8F2O2
MW:246.21
EINECS:
Product Categories:Aryl Fluorinated Building Blocks;Bioactive Small Molecules;Building Blocks;C13 to C14;C13-C26;Carbonyl Compounds;C13 to C14;Cell Biology;Chemical Synthesis;D-DIF;Fluorinated Building Blocks;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;Aromatic Halides (substituted);Carbonyl Compounds;Ketones
Mol File:579-39-5.mol
4,4'-DIFLUOROBENZIL Chemical Properties
Melting point 120-122 °C (lit.)
Boiling point 370.2±27.0 °C(Predicted)
density 1.3163 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color Light orange to Yellow to Green
Water Solubility Soluble in water.
BRN 1971736
CAS DataBase Reference579-39-5(CAS DataBase Reference)
EPA Substance Registry SystemEthanedione, bis(4-fluorophenyl)- (579-39-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
Hazard Note Irritant
TSCA T
HS Code 29147000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4,4'-DIFLUOROBENZIL Usage And Synthesis
Chemical Propertiespale yellow powder
Uses4,4′-Difluorobenzil is suitable for use in the preparation of 2,3-bis(4-fluorophenyl)thieno[3,4-b]pyrazine. It may be used in the synthesis of following:
  • poly(ether-α-diketone)s, via nucleophilic substitution reaction with bisphenol A
  • 4,4′-difluoro-2,3-diphenylpyrazine (DPPF) and 4,4′-difluoro-5-methyl 2,3-diphenylpyrazine (MDPPF), via direct condensation with ethylenediamine and 1,2-diaminopropane, respectively
  • 2,3-bis(4-fluorophenyl)quinoxaline, via direct condensation with 1,2-phenylenediamine
Synthesis Reference(s)Tetrahedron Letters, 35, p. 2959, 1994 DOI: 10.1016/S0040-4039(00)76671-8
General Description4,4′-Difluorobenzil is a benzil derivative. Its reaction with benzylurea and phenethylurea has been investigated. It is reported to undergo condensation with Fe2(SH)2(CO)6 to afford the adduct Fe2[S2C2(OH)2(C6H4-4-F)2](CO)6.
4,4'-DIFLUOROBENZIL Preparation Products And Raw materials
Raw materialsBenzene, 1,1'-ethenylidenebis[4-fluoro--->1,2-BIS-(4-FLUOROPHENYL)ETHANONE

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