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| (1R,1'R,2S,2'S)-DUANPHOS Basic information | | Reactions |
| Product Name: | (1R,1'R,2S,2'S)-DUANPHOS | | Synonyms: | (1R,1'R,2S,2'S)-2,2'-Bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-1,1'-bi-1H-isophosphindole,99%e.e.;(1R,1'R,2S,2'S)- 2,2'-bis(1,1-diMethylethyl)-2,2',3,3'-tetrahydro-1,1'-Bi-1H-isophosphindole;(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole (R,R,S,S)-DUANPHOS;RcSp-DuanPhos;1,1'-Bi-1H-isophosphindole, 2,2'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (1R,1'R,2S,2'S)-;(1R,1'R,2S,2'S)-2,2'-di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biisophosphindole | | CAS: | 528814-26-8 | | MF: | C24H32P2 | | MW: | 382.46 | | EINECS: | | Product Categories: | | Mol File: | 528814-26-8.mol |
| (1R,1'R,2S,2'S)-DUANPHOS Chemical Properties |
| Melting point | 214-246 °C | | alpha | +19.5 | | Boiling point | 474.5±45.0 °C(Predicted) | | form | crystal | | color | white | | optical activity | [α]20/D +18°, c = 1 in chloroform | | Sensitive | air sensitive | | CAS DataBase Reference | 528814-26-8 |
| (1R,1'R,2S,2'S)-DUANPHOS Usage And Synthesis |
| Reactions |
- As a highly electron-donating and conformationally rigid ligand, the rhodium complex of DuanPhos has exhibited remarkably high enantioselectivities and reactivities for the hydrogenation of a variety of functionalized olefins.
- Rhodium/DUANPHOS catalyst used in the synthesis of 2-trifluoromethyl lactic acid by asymmetric hydroformylation.
| | Uses | Chiral Quest Phosphine Ligands for Asymmetric HydrogenationCatalytic ligand used for:- Stereoselective synthesis of cyano-substituted dihydropyrroles by annulation of cyanoallenes
- Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
- Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
- Stereoselective preparation of anti-1,3-amino alcohols via rhodium-catalyzed asymmetric hydrogenation of β-ketoenamide intermediates
- Stereoselective preparation of acetylaminoindane via rhodium-catalyzed asymmetric hydrogenation of acetylaminoindene
| | General Description | (1R,1′R,2S,2′S)-DuanPhos is an electron-rich chiral phosphine ligand mainly for transition metal catalyzed asymmetric hydrogenation. |
| (1R,1'R,2S,2'S)-DUANPHOS Preparation Products And Raw materials |
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