TRANS-2-METHYL-2-BUTENAL
TRANS-2-METHYL-2-BUTENAL
  • CAS No.:497-03-0
Other grades of this product :
TRANS-2-METHYL-2-BUTENAL Basic information
Product Name:TRANS-2-METHYL-2-BUTENAL
Synonyms:(2E)-2-Methyl-2-butenal;(E)-2-Methyl-2-butenal;(E)-2-methylbut-2-en-1-al;(E)-2-methylbut-2-enal;2,2-Dimethylacrolein;2-Butenal,2-methyl-,(2E)-;2-Butenal,2-methyl-,(E)-;2-methyl-(E)-2-butenal
CAS:497-03-0
MF:C5H8O
MW:84.12
EINECS:207-833-0
Product Categories:
Mol File:497-03-0.mol
TRANS-2-METHYL-2-BUTENAL Chemical Properties
Melting point -101.15°C (estimate)
Boiling point 116-119 °C752 mm Hg(lit.)
density 0.871 g/mL at 25 °C(lit.)
refractive index n20/D 1.448(lit.)
FEMA 3407 | 2-METHYL-2-BUTENAL
Fp 65 °F
storage temp. Flammables area
form Liquid
color Clear colorless to yellow
Water Solubility Soluble in water
Sensitive Air Sensitive
JECFA Number1201
BRN 1698207
CAS DataBase Reference497-03-0(CAS DataBase Reference)
EPA Substance Registry Systemtrans-2-Methylcrotonaldehyde (497-03-0)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38-10
Safety Statements 16-26-36
RIDADR UN 1989 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29121990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRANS-2-METHYL-2-BUTENAL Usage And Synthesis
Description2-Methyl-2-butenal has a penetrating, powerful green ethereal odor. May be prepared by condensation of acetaldehyde and propionaldehyde.
Chemical Propertiesclear colorless to yellow liquid
UsesTiglic aldehyde was used in the concise total synthesis of 7-demethylpiericidin A1. It was used as starting reagent during the synthesis of:
  • alkyl-branched tetraene hydrocarbons, pheromone component for dried fruit beetle
  • E,E-2,4-dimethyl-2,4-hexa dienal, volatile constituents of the defensive secretions ofLeiobunum nigripalpi
  • 4-methyl-2,4-hexadiene-1-ol
General Descriptiontrans-2-Methyl-2-butenal is one of the major volatile constituents of coriander and olive oil.
TRANS-2-METHYL-2-BUTENAL Preparation Products And Raw materials

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