METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE
METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE
  • CAS No.:4707-47-5
Other grades of this product :
METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE Basic information
Product Name:METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE
Synonyms:MOUSSE DE METRA;VERAMOSS;VERAMOSS SPS;2,4-dihydroxy-3,6-dimethyl-benzoicacimethylester;Atraric acid;Benzoic acid, 2,4-dihydroxy-3,6-dimethyl-, methyl ester;Benzoicacid,2,4-dihydroxy-3,6-dimethyl-,methylester;Methyl 3,6-dimethyl-beta-resorcylate
CAS:4707-47-5
MF:C10H12O4
MW:196.2
EINECS:225-193-0
Product Categories:Alphabetical Listings;Flavors and Fragrances;M-N
Mol File:4707-47-5.mol
METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE Chemical Properties
Melting point 141-146 °C (lit.)
Boiling point 360.7±22.0 °C(Predicted)
density 1.251±0.06 g/cm3(Predicted)
vapor pressure 0.002Pa at 24℃
storage temp. Store below +30°C.
pka8.63±0.28(Predicted)
Water Solubility 18mg/L at 24℃
LogP2.6 at 25℃
CAS DataBase Reference4707-47-5(CAS DataBase Reference)
EPA Substance Registry SystemBenzoic acid, 2,4-dihydroxy-3,6-dimethyl-, methyl ester (4707-47-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 2
TSCA Yes
HS Code 2918 29 00
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE Usage And Synthesis
Chemical PropertiesMethyl 3,6-Dimethylresorcylate is an odor-determining constituent of oakmoss absolute extract and forms colorless crystals (mp 145°C) with a mossy–earthy odor.
UsesMethyl atratate is used in biological study as role of androgens in inducing distinct response of epithelial-mesenchymal transition factors in human prostate cancer cells.
PreparationMethyl 3,6-dimethylresorcylate is prepared by aromatization of corresponding hydroxycyclohexenones, for example, by dehydrogenation with a suitable Nhaloimide.The intermediate hydroxycyclohexenone can be obtained either by reaction of dimethylmalonate with 4-hexen-3-one and 5-chloro-3-hexanone or by reaction of methyl propionylacetate with alkyl crotonate.Another route starts from the corresponding dimethyl-1,3-dihydroxybenzene, which is carboxylated, and the resulting dihydroxymethylbenzoic acid is esterified.
Flammability and ExplosibilityNotclassified
Trade nameAtralone (Agan)
METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE Preparation Products And Raw materials
Preparation Products3-CHLORO-2,6-DIHYDROXY-4-METHYLBENZALDEHYDE

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