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| Acetylthiomethyl-diphenylphosphine borane complex Basic information |
| Acetylthiomethyl-diphenylphosphine borane complex Chemical Properties |
| Melting point | 52-55 °C | | storage temp. | 2-8°C |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 |
| Acetylthiomethyl-diphenylphosphine borane complex Usage And Synthesis |
| Uses | Traceless Staudinger ligation reagent with borane protecting group. The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine. After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond. Used in the synthesis of cyclic peptides. | | Uses | - Traceless Staudinger ligation reagent with borane protecting group.
- The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
- After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
- Used in the synthesis of cyclic peptides.
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| Acetylthiomethyl-diphenylphosphine borane complex Preparation Products And Raw materials |
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