3-BENZYLIDENE-2,4-PENTANEDIONE
3-BENZYLIDENE-2,4-PENTANEDIONE
  • CAS No.:4335-90-4
Other grades of this product :
3-BENZYLIDENE-2,4-PENTANEDIONE Basic information
Product Name:3-BENZYLIDENE-2,4-PENTANEDIONE
Synonyms:3-(phenylmethylidene)pentane-2,4-dione;3-Benzylidenepentane-2,4-Dione;3-BENZYLIDENE-2,4-PENTANEDIONE;3-Benzylidine-2,4-pentanedione;(2,2-diacetylvinyl)benzene;1,1-Diacetyl-2-phenylethylene;2,4-Pentanedione, 3-(phenylmethylene)-;2,4-Pentanedione, 3-benzylidene-
CAS:4335-90-4
MF:C12H12O2
MW:188.22
EINECS:224-382-5
Product Categories:Carbonyl Compounds;Chemical Synthesis;C11 to C12;Building Blocks;C11 to C12;Organic Building Blocks;Carbonyl Compounds;Ketones
Mol File:4335-90-4.mol
3-BENZYLIDENE-2,4-PENTANEDIONE Chemical Properties
Melting point 169 °C
Boiling point 185-188 °C/15 mmHg (lit.)
density 1.081 g/mL at 25 °C (lit.)
refractive index n20/D 1.583(lit.)
Fp >230 °F
Specific Gravity1.081
BRN 972849
CAS DataBase Reference4335-90-4(CAS DataBase Reference)
EPA Substance Registry System2,4-Pentanedione, 3-(phenylmethylene)- (4335-90-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS SA1930000
TSCA Yes
HS Code 2914390090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-BENZYLIDENE-2,4-PENTANEDIONE Usage And Synthesis
Uses3-Benzylidene-2,4-pentanedione may be used in the preparation of:
  • Five membered cyclic oxyphosphoranes by reacting with phosphonite esters.
  • 5-Hydroxy-N-substituted-2H-pyrrol-2-ones by reacting with alkyl isocyanides.
  • 3-Benzylidene-2,4-bis (trimethylsilyloxy)-1,4-pentadiene via trimethylsilylation.
Synthesis Reference(s)Synthetic Communications, 26, p. 3025, 1996 DOI: 10.1080/00397919608004607
General Description3-Benzylidene-2,4-pentanedione (BPD) can be prepared by reacting benzaldehyde with 2,4-pentanedione in the presence of a base.
3-BENZYLIDENE-2,4-PENTANEDIONE Preparation Products And Raw materials
Preparation Productstrans,trans-Dibenzylideneacetone

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