| RUTHENIUM CARBONYL Basic information |
| Reactions |
| Product Name: | RUTHENIUM CARBONYL |
| Synonyms: | dodecacarbonyltri-rutheniutriangulo;Ru3(CO)12;TrirutheniuM dodecacarbonyl 99%;Trirutheniumdodecarbonyl(DCR);pentaoxonium;Ruthenium, dodecacarbonyltri-, triangulo;Ruthenium,dodecacarbonyltri-;DODECACARBONYLTRIRUTHENIUM |
| CAS: | 15243-33-1 |
| MF: | C12O12Ru3 |
| MW: | 639.33 |
| EINECS: | 239-287-4 |
| Product Categories: | Ru;Classes of Metal Compounds;Ru (Ruthenium) Compounds;Transition Metal Compounds;metal carbonyl complexes |
| Mol File: | 15243-33-1.mol |
| RUTHENIUM CARBONYL Chemical Properties |
| Melting point | 150 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
| form | crystal |
| color | orange |
| CAS DataBase Reference | 15243-33-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1) |
| Safety Information |
| Hazard Codes | F,Xn |
| Risk Statements | 11-20-2017/11/20 |
| Safety Statements | 24/25 |
| RIDADR | 1325 |
| WGK Germany | 3 |
| Hazard Note | Flammable/Harmful |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 28439000 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| RUTHENIUM CARBONYL Usage And Synthesis |
| Reactions |
|
| Chemical Properties | orange plates |
| Uses | A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF). |
| General Description | Atomic number of base material: 44 Ruthenium |
| RUTHENIUM CARBONYL Preparation Products And Raw materials |
| Raw materials | ruthenium pentacarbonyl-->Trifluoromethanesulfonic acid-->Ruthenium(III) chloride |
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