Boron trifluoride-methanol solution
Boron trifluoride-methanol solution
  • CAS No.:373-57-9
Other grades of this product :

Boron trifluoride-methanol solution Basic information
Product Name:Boron trifluoride-methanol solution
Synonyms:Boron Trifluoride in Methanol;Boron Trifluoride, 50-55wt.% in Methanol;Boron trifluoride-Methanol solution,50-55%;Boron trifluoride, 12% (1.5M) in Methanol;Boron trifluoride, 12% (1.5M) in Methanol, AcroSeal;Boron trifluoride Methanol, 50 wt.% solution in MeOH;BF3/METHANOL;BORON TRIFLUORIDE-METHANOL
CAS:373-57-9
MF:CH3BF3O
MW:98.84
EINECS:206-766-4
Product Categories:Fine Chemical;BoronMicro/Nanoelectronics;BoronSynthetic  Reagents;Electronic  Chemicals;Lewis  Acids;Catalysis  and  Inorganic  Chemistry;Analytical Chemistry;BCl3, BF3, HCl-Alkanol Solutions (GC Derivatizing Reagents);Esterification & Alkylation (GC Derivatizing Reagents);GC Derivatizing Reagents;Chemical  Synthesis;Fluorides;Acylation  ReagentsDerivatization  Reagents;Reagents  for  Alkylation&Esterification;B (Classes of Boron Compounds);Boron Trifluorides;Boron Trihalides;Analytical/Chromatography;Derivatization  Reagents;Derivatization  Reagents  GC;Reagents  for  Acylation;Boron
Mol File:373-57-9.mol
Boron trifluoride-methanol solution Chemical Properties
Melting point -93℃ (Methanol)
Boiling point 59 °C4 mm Hg
density 1.203 g/mL at 25 °C
vapor pressure 19.5 mm Hg ( 20 °C)
refractive index n20/D1.328
Fp 52 °F
storage temp. 2-8°C
form clear liquid
Specific Gravity0.890 (20/4℃)
color Colorless to Light yellow
Merck 14,1349
BRN 3611499
InChIKeyFQZVTMBNNNQKJY-UHFFFAOYSA-N
CAS DataBase Reference373-57-9
EPA Substance Registry SystemBoron, trifluoro(methanol)-, (T-4)- (373-57-9)
Safety Information
Hazard Codes T,C,T+,F
Risk Statements 20/22-34-48/23-39/23/24/25-35-26-24/25-11-14-23/24/25
Safety Statements 26-28-36/37/39-45-23-16
RIDADR UN 3286 3/PG 2
WGK Germany 3
RTECS ED2275000
21
Autoignition Temperature788 °F
HazardClass 8
PackingGroup I
HS Code 28129019
MSDS Information
ProviderLanguage
SigmaAldrichEnglish
ACROSEnglish
ALFAEnglish
Boron trifluoride-methanol solution Usage And Synthesis
Chemical Propertiescolorless to amber solution
Chemical PropertiesBoron trifluoride etherates: (compounded with methyl ether) is moisture-sensitive, corrosive, flammable liquid.
UsesTrifluoro(methanol)boron is a reagent used for the GC analysis of ritalinic acid.
UsesReagent for the GC analysis of ritalinic acid. Alternative to Cl2CHCO2H for synthesis of purine rich oligomers.Lewis acid used in the preparation of geminal bis-peroxides from ketals and enol ethers with t-butyl hydroperoxide. Reagent used for the mild deacetylation of amines.
UsesIt was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may be used to treat lipids during GC analysis done for determination of fatty acid methyl esters and dimethylacetals.
General DescriptionBoron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.
Potential ExposureUsed as a catalyst.
ShippingDiethyl: UN2604 Boron trifluoride diethyl etherate, Hazard class: 8; Labels: 8—Corrosive material, 3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride dimethyl etherate, Hazard class: 4.3; Labels: 4.3— Dangerous when wet, 8—Corrosive material, 3— Flammable liquid.
IncompatibilitiesReacts with air forming corrosive hydrogen fluoride vapors. Incompatible with oxidizers (may cause fire and explosion), water, steam or heat, forming corrosive and flammable vapors. Peroxide containing etherate reacts explosively with aluminum lithium hydride, magnesium tetrahydroaluminate. Mixtures with phenol react explosively with 1,3-butadiene. Presumed to form explosive peroxides.
Boron trifluoride-methanol solution Preparation Products And Raw materials
Preparation ProductsTrimethyl borate

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