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| (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Basic information |
| Product Name: | (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER | | Synonyms: | 4S,5S-diethyl 2,2-diMethyl-1,3-dioxolane-4,5-dicarboxylate;Dimethyl (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylate
(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic Acid Dimethyl Ester
(+)-2,3-O-Isopropylidene-D-tartaric Acid Dimethyl Ester;2,2-Dimethyl-(4S-trans)-1,3-Dioxolane-4,5-dicarboxylic acid dimethyl ester;Dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester;(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate,97%;(+)-DiMethyl 2,3-O-isopropylidene-D-tartarate , GC 97%;(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate 98%;(4S,5S)- 2,2-dimethyl-1,3-Dioxolane-4,5-dicarboxylic acid 4,5-dimethyl ester | | CAS: | 37031-30-4 | | MF: | C9H14O6 | | MW: | 218.2 | | EINECS: | | Product Categories: | chiral;Amino Acids 13C, 2H, 15N;Chiral Building Blocks;Dioxanes & Dioxolanes;Dioxolanes;Esters (Chiral);Synthetic Organic Chemistry;Amino Acids & Derivatives | | Mol File: | 37031-30-4.mol |
| (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Chemical Properties |
| Boiling point | 80-82 °C0.1 mm Hg(lit.) | | alpha | [α](c=1, CHCl3) +41.0～+45.0° | | density | 1.19 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.439(lit.) | | Fp | 275 °F | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform, Methanol | | form | Liquid | | color | Clear colorless to slightly yellow | | optical activity | [α]20/D +54°, neat | | BRN | 3548490 | | InChIKey | MCNKHXZIPATURB-YUMQZZPRSA-N | | CAS DataBase Reference | 37031-30-4(CAS DataBase Reference) |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | F | 21 | | HS Code | 29329900 |
| (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of: - Deuterated 1-deoxy-D-xylose.
- C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS).
- Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.
| | General Description | (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138] |
| (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Preparation Products And Raw materials |
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