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| (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Basic information | | Uses |
| Product Name: | (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole | | Synonyms: | (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline;(4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole;(S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole;(4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole,99%e.e.;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline,98%;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%;(S)-t-BuPHOX | | CAS: | 148461-16-9 | | MF: | C25H26NOP | | MW: | 387.45 | | EINECS: | | Product Categories: | Chiral Phosphine;PHOX Series | | Mol File: | 148461-16-9.mol |
| (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Chemical Properties |
| Melting point | 111-116 °C | | Boiling point | 498.9±28.0 °C(Predicted) | | storage temp. | -20°C | | pka | 4.44±0.70(Predicted) | | optical activity | [α]22/D -57.0°, c = 1 in chloroform |
| Safety Statements | 24/25 | | WGK Germany | 3 | | HS Code | 29319090 |
| (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Usage And Synthesis |
| Uses | (S)-4-Tert-Butyl-2-(2-(Diphenylphosphino)Phenyl)-4,5-Dihydrooxazole (cas# 148461-16-9) is a useful research chemical. | | Chemical Properties | Colorless solid | | Uses | (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline can be used as a ligand for enantioselective Heck reaction without any C=C double bond migration byproduct. It can also be used in a rhodium(I)-catalyzed enantioselective desymmetrization reaction of meso-3,5-dimethyl glutaric anhydride, to form substituted syn-deoxypolypropionate fragments in a single transformation. | | General Description | The product is a phosphinooxazoline (PHOX) ligand introduced by Pfaltz and coworkers. These non-symmetrical modular P,N-ligands are particularly useful in cases where double bond migration leads to undesired products or mixtures of isomers. |
| (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Preparation Products And Raw materials |
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![(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole](/img/148461-16-9.jpg "(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole")
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