| (METHOXYMETHYL)TRIMETHYLSILANE Basic information |
| Product Name: | (METHOXYMETHYL)TRIMETHYLSILANE |
| Synonyms: | trimethylsilyl methyl ether;Trimethyl(methoxymethyl)silane;Silane, (methoxymethyl)trimethyl-;TRIMETHYLSILYLMETHYL METHYL ETHER;(METHOXYMETHYL)TRIMETHYLSILANE;(METHOXYMETHYL)TRIMETHYLSILANE 95%;Methoxymethyltrimethylsilane> |
| CAS: | 14704-14-4 |
| MF: | C5H14OSi |
| MW: | 118.25 |
| EINECS: | |
| Product Categories: | Synthetic Organic Chemistry;Biochemistry;Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis) |
| Mol File: | 14704-14-4.mol |
| (METHOXYMETHYL)TRIMETHYLSILANE Chemical Properties |
| Melting point | <0°C |
| Boiling point | 83 °C/740 mmHg (lit.) |
| density | 0.758 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 8 °F |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.755 |
| Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems |
| BRN | 1732033 |
| CAS DataBase Reference | 14704-14-4(CAS DataBase Reference) |
| NIST Chemistry Reference | (Methoxymethyl)trimethylsilane(14704-14-4) |
| Safety Information |
| Hazard Codes | F,Xi |
| Risk Statements | 11-36/37/38 |
| Safety Statements | 16-26-28-29-33-36/37/39 |
| RIDADR | UN 3271 3/PG 2 |
| WGK Germany | 3 |
| TSCA | No |
| HazardClass | 3.1 |
| PackingGroup | II |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| (METHOXYMETHYL)TRIMETHYLSILANE Usage And Synthesis |
| Purification Methods | It forms an azeotrope with MeOH (b 60o). If it contains MeOH (check IR for bands above 3000cm-1), then wash with H2O and fractionate. A possible impurity could be chloromethyl trimethylsilane (b 97o/740mm). [Speier J Am Chem Soc 70 4142 1948, Beilstein 4 III 1844.] It is an IRRITATING FLAMMABLE liquid. |
| (METHOXYMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials |
| Raw materials | (TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE-->Methanol-->Dimethyl ether-->Sodium methoxide-->Chloromethyltrimethylsilane-->Chloromethyl methyl ether-->Chlorotrimethylsilane |
| Preparation Products | METHYL FLUORIDE-->METHOXYTRIMETHYLSILANE |
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