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| (R)-(-)-Benzyl glycidyl ether Basic information |
| (R)-(-)-Benzyl glycidyl ether Chemical Properties |
| Melting point | 88-93°C | | Boiling point | 130 °C (0.1 mmHg) | | alpha | -5.4 º (c=5 in toluene) | | density | 1.077 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.517(lit.) | | Fp | >230 °F | | storage temp. | 2-8°C | | form | paste (yellow) | | Specific Gravity | 1.077 | | color | Colorless to Almost colorless | | optical activity | [α]20/D 5.4°, c = 5 in toluene | | Water Solubility | Soluble in water. | | BRN | 3588399 | | CAS DataBase Reference | 14618-80-5(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-37/39 | | RIDADR | NA 1993 / PGIII | | WGK Germany | 3 | | RTECS | TX2860020 | | HS Code | 29109000 | | Toxicity | mic-sat 660 nmol/plate MUREAV 298,197,1993 |
| (R)-(-)-Benzyl glycidyl ether Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin. | | Synthesis Reference(s) | Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6 | | General Description | 1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst. | | Safety Profile | Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors. | | Purification Methods | This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.] |
| (R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials |
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