ETHYL 2-NITROPROPIONATE
ETHYL 2-NITROPROPIONATE
  • CAS No.:2531-80-8
Other grades of this product :
ETHYL 2-NITROPROPIONATE Basic information
Product Name:ETHYL 2-NITROPROPIONATE
Synonyms:2-nitro-propanoicaciethylester;Propanoic acid, 2-nitro-, ethyl ester;Propionic acid, 2-nitro-, ethyl ester;Ethyl alpha-nitropropionate;Nsc 63896;ethyl 2-nitropropanoate;Ethyl 2-nitropropionate 96%;Ethyl 2-nitropropiote, 96%
CAS:2531-80-8
MF:C5H9NO4
MW:147.13
EINECS:
Product Categories:C2 to C5;Carbonyl Compounds;Esters
Mol File:2531-80-8.mol
ETHYL 2-NITROPROPIONATE Chemical Properties
Boiling point 75-76 °C/9 mmHg (lit.)
density 1.13 g/mL at 25 °C (lit.)
refractive index n20/D 1.421(lit.)
Fp 193 °F
pka5.98±0.10(Predicted)
Water Solubility Not miscible in water.
BRN 774734
EPA Substance Registry SystemPropanoic acid, 2-nitro-, ethyl ester (2531-80-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RIDADR NA 1993 / PGIII
WGK Germany 3
TSCA Yes
HazardClass IRRITANT
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
ETHYL 2-NITROPROPIONATE Usage And Synthesis
UsesEthyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions.
UsesEthyl 2-nitropropionate was used in the preparation of:
  • (?)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst
  • novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion
  • 2-ethoxycarbonyl-2-nitropentanal
General DescriptionEthyl 2-nitropropionate is a nitro ester.
ETHYL 2-NITROPROPIONATE Preparation Products And Raw materials

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