GERMANIUM(IV) ETHOXIDE
GERMANIUM(IV) ETHOXIDE
  • CAS No.:14165-55-0
Other grades of this product :
GERMANIUM(IV) ETHOXIDE Basic information
Product Name:GERMANIUM(IV) ETHOXIDE
Synonyms:GERMANIUM ETHOXIDE;GERMANIUM ETHYLATE;GERMANIUM(IV) ETHOXIDE;GERMANIUM TETRAETHOXIDE;Germanium(IV)ethoxide, 99.95+%;TETRAETHYOXYGERMANE;Germanium(IV) ethoxide, 99.995% (metals basis);Orthogermanic acid tetraethyl ester
CAS:14165-55-0
MF:C8H20GeO4
MW:252.88
EINECS:238-007-8
Product Categories:metal alkoxide
Mol File:14165-55-0.mol
GERMANIUM(IV) ETHOXIDE Chemical Properties
Melting point -72°C
Boiling point 185-6°C
density 1.14 g/mL at 25 °C(lit.)
refractive index n20/D 1.407(lit.)
Fp 121 °F
form Liquid
color Colorless
Specific Gravity1.134
Water Solubility Soluble in anhydrous alcohol and benzene. Hydrolyzes in water
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 3661173
CAS DataBase Reference14165-55-0(CAS DataBase Reference)
EPA Substance Registry SystemEthanol, germanium(4+) salt (14165-55-0)
Safety Information
Hazard Codes T,Xi
Risk Statements 10-36/37/38-23/24/25
Safety Statements 26-36-45-36/37/39-27-16
RIDADR UN 1993 3/PG 3
WGK Germany 3
10-21
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 2905190019
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
GERMANIUM(IV) ETHOXIDE Usage And Synthesis
Chemical Propertiesclear colorless to very light yellow liquid
UsesIt is a sol-gel intermediate for optical fibers and photosensitive.
Purification MethodsDistil it through a 10cm Vigreux column (p 11) under reduced pressure. Alternatively distil it through a Fenske glass helices (p 11) column fitted with a total condensation variable take-off stillhead. Fractionate it under reduced pressure using a reflux ratio of 10:1. [Johnson & Fritz J Am Chem Soc 75 718 1953, Bradley J Chem Soc 4916 1956, Beilstein 1 IV 1308.]
GERMANIUM(IV) ETHOXIDE Preparation Products And Raw materials

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